Emergence of chiral environments by effect of flows: The case of an ionic oligomer and Congo red dye

Okano K.; Arteaga O.; Ribo J.M.; Yamashita T.

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Emergence of chiral environments by effect of flows: The case of an ionic oligomer and Congo red dye

机译：通过流动的影响出现手性环境：离子低聚物和刚果红染料的情况

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Mechanical chiral induction: In aqueous solutions of a cationic oligomer that forms interchain cross-linking through non-covalent interactions, chiral regions can be obtained reversibly by stirring flows. The chiral induction upon an achiral molecule (Congo Red dye) was demonstrated by Mueller matrix spectroscopy analysis of the optical polarization properties. Shown here is the true CD image of a stirred solution, clockwise (top) and counterclockwise (bottom), of compound 1.

机译：机械手性诱导：在阳离子低聚物通过非共价相互作用形成链间交联的水溶液中，通过搅拌流可逆地获得手性区域。通过非偏振手性分子（刚果红染料）的手性诱导通过Mueller矩阵光谱法分析了其光学偏振特性。此处显示的是化合物1沿顺时针方向（顶部）和逆时针方向（底部）搅拌的溶液的真实CD图像。

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《Chemistry: A European journal》 |2011年第34期|共5页
作者
Okano K.; Arteaga O.; Ribo J.M.; Yamashita T.;
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正文语种 eng
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chirality; circular dichroism; ionic oligomer; vortex flow;

机译：手性圆二色性离子低聚物涡流;

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1. Emergence of chiral environments by effect of flows: The case of an ionic oligomer and Congo red dye [J] . Okano K., Arteaga O., Ribo J.M., Chemistry: A European journal . 2011,第34期

机译：通过流动的影响出现手性环境：离子低聚物和刚果红染料的情况
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Emergence of chiral environments by effect of flows: The case of an ionic oligomer and Congo red dye

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