Direct arylation of alkenes with aryl iodides/bromides through an organocatalytic radical process

Sun C.-L.; Gu Y.-F.; Wang B.; Shi Z.-J.

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Direct arylation of alkenes with aryl iodides/bromides through an organocatalytic radical process

机译：通过有机催化自由基过程，烯烃与芳基碘化物/溴化物直接芳基化

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A radical addition: A KOtBu-complex-promoted radical arylation of polysubstituted alkenes with aryl iodides/bromides proceeds in high efficiency (see scheme). Benzofuran derivatives are also produced starting from readily available allyl 2-iodophenyl ethers.

机译：自由基加成：高效进行多取代烯烃与芳基碘化物/溴化物的KOtBu络合物促进的自由基芳基化（请参阅方案）。苯并呋喃衍生物也从容易获得的烯丙基2-碘苯基醚开始生产。

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《Chemistry: A European journal》 |2011年第39期|共4页
作者
Sun C.-L.; Gu Y.-F.; Wang B.; Shi Z.-J.;
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正文语种 eng
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alkenes; benzofuran; C-C addition; organocatalysis; radicals;

机译：烯烃;苯并呋喃;C-C加成;有机催化;自由基;

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专利

1. Direct Arylation of Alkenes with Aryl Iodides/Bromides through an Organocatalytic Radical Process [J] . Chang-Liang Sun, Yi-Fan Gu, Prof. Dr. Bin Wang, Chemistry - A European Journal . 2011,第39期

机译：通过有机催化自由基过程将芳烃与碘化物/溴化物直接芳基化
2. Copper(I)Thiophene-2-carboxylate(CuTC):A Versatile Non-Nitrogen Ligand-Based Catalyst for Direct N-Arylation of Imidazole and Pyrazole Using Aryl Iodides,Aryl Bromides,and Aryl Chlorides [J] . Hariharasarma Maheswaran, Gaddamanugu, Gopi Krishna Bulletin of the Chemical Society of Japan . 2008,第4期

机译：噻吩-2-羧酸铜（I）-多功能非氮配体基催化剂，用于使用芳基碘化物，芳基溴化物和芳基氯化物对咪唑和吡唑进行直接N-芳基化
3. Highly regioselective ruthenium-catalyzed direct arylation of thiazolo [3,2-b]-1,2,4-triazoles with aryl iodides and aryl bromides via CeH bond activation [J] . Huiping Zhang Journal of Organometallic Chemistry . 2014,第Null期

机译：噻唑并[3,2-b] -1,2,4-三唑通过CeH键活化与芳基碘化物和芳基溴化物一起进行高度区域选择性的钌催化直接芳基化
4. Microwave-Assisted Palladium-Catalyzed Direct Arylation of 1,2,3-Triazoles with Aryl Chlorides [C] . Masayuki Iwasaki, Hideki Yorimitsu, Koichiro Oshima Symposium on Organometallic Chemistry . 2007

机译：微波辅助钯催化的1,2,3-三唑与芳基氯化物的直接芳基
5. Catalyst development for the direct arylation of aryl chlorides, bromides and iodides. [D] . Parisien, Mathieu. 2006

机译：芳基氯，溴化物和碘化物直接芳基化的催化剂开发。
6. Pd(II)-catalyzed ortho arylation of 2-arylbenzothiazoles with aryl iodides via benzothiazole-directed C–H activation [O] . Qiuping Ding, Huafang Ji, Dan Wang, -1

机译：Pd（II）通过苯并噻唑定向的C–H活化催化2-芳基苯并噻唑与芳基碘的邻位芳基化
7. Copper-catalysed N-arylation of arylsulfonamides with aryl bromides and aryl iodides using KF/Al2O3 [O] . Rahman Hosseinzadeh, Mahmood Tajbakhsh, Maryam Mohadjerani, 2010

机译：铜催化的芳基磺胺酰胺与芳溴酰胺和芳基碘化物使用Kf / Al2O3的芳基碘化物
8. Preparation of F-Cadmium Reagents Directly from F-Alkyl Iodides and F-Aryl Bromide and Cadmium Metal [R] . Heinze, P. L., Burton, D. J. 1985

机译：直接由F-烷基碘化物和F-芳基溴化物和镉金属制备F-镉试剂

Direct arylation of alkenes with aryl iodides/bromides through an organocatalytic radical process

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