Microenvironment engineering in ortho- and para-dendronized metalloporphyrin-fullerene conjugates involving a trans-2-bisaddition pattern

Ruppert M.; Bauer W.; Hirsch A.

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Microenvironment engineering in ortho- and para-dendronized metalloporphyrin-fullerene conjugates involving a trans-2-bisaddition pattern

机译：涉及反式2-双加成模式的邻-和对-双-枝状金属卟啉-富勒烯共轭物的微环境工程

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摘要

A new series of dendronized metalloporphyrin-fullerene conjugates as photosynthetic reaction center mimics was developed in a highly regioselective fashion through tether-controlled synthesis. The microenvironment around the porphyrin core is dependent on the spatial substitution pattern and the nature and generation number of the dendrons, which was proven by cyclic voltammetry.

机译：通过束缚控制合成，以高度区域选择性的方式开发了一系列新的树枝状金属卟啉-富勒烯共轭物，作为光合作用反应中心模拟物。卟啉核周围的微环境取决于空间取代模式以及树枝状分子的性质和世代数，这已通过循环伏安法证明。

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《Chemistry: A European journal》 |2011年第31期|共12页
作者
Ruppert M.; Bauer W.; Hirsch A.;
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正文语种 eng
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关键词
cyclic voltammetry; dendrimers; fullerenes; porphyrins;

机译：循环伏安法;树状大分子;富勒烯;卟啉;

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1. Microenvironment engineering in ortho- and para-dendronized metalloporphyrin-fullerene conjugates involving a trans-2-bisaddition pattern [J] . Ruppert M., Bauer W., Hirsch A. Chemistry: A European journal . 2011,第31期

机译：涉及反式2-双加成模式的邻-和对-双-枝状金属卟啉-富勒烯共轭物的微环境工程
2. Dendritic metalloporphyrin-fullerene conjugates: Changing the microenvironment around redox-active centers and its impact on charge-transfer reactions [J] . Krokos E., Sp?nig F., Ruppert M., Chemistry: A European journal . 2012,第33期

机译：树突状金属卟啉-富勒烯共轭物：改变氧化还原活性中心周围的微环境及其对电荷转移反应的影响
3. Metal-Atom Impact on the Self-Assembly of Cup-and-Ball Metalloporphyrin-Fullerene Conjugates [J] . Moreira Luis, Calbo Joaquin, Illescas Beatriz M., Angewandte Chemie . 2015,第4期

机译：金属原子对杯球金属卟啉-富勒烯共轭物自组装的影响
4. Engineering the microenvironment of crystals nucleation and growth using micropatterned polymers [C] . Joanna Alzenberg, Andrew J.Black, George M.Whitesides ACS Polymeric Materials Science and Engineering Meeting . 1999

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Microenvironment engineering in ortho- and para-dendronized metalloporphyrin-fullerene conjugates involving a trans-2-bisaddition pattern

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