Highly enantioselective henry reactions in water catalyzed by a copper tertiary amine complex and applied in the synthesis of (S)-N-trans-feruloyl octopamine

Lai G.; Guo F.; Zheng Y.; Fang Y.; Song H.; Xu K.; Wang S.; Zha Z.; Wang Z.

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Highly enantioselective henry reactions in water catalyzed by a copper tertiary amine complex and applied in the synthesis of (S)-N-trans-feruloyl octopamine

机译：铜叔胺络合物催化的水中高度对映选择性亨利反应，用于合成（S）-N-反式-阿魏酸章鱼胺

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摘要

It's in the water! A new copper tertiary amine complex was prepared and applied in asymmetric Henry reactions in water and in the short synthesis of (S)-N-trans-feruloyl octopamine. This catalytic system provided an approach to the enantioselective Henry reaction of aldehydes with hydroxyl substituents (see graphic).

机译：在水里！制备了一种新的铜叔胺络合物，并将其用于水中的不对称亨利反应中，以及在短时间内合成（S）-N-反式-阿魏酰基章鱼胺中。该催化体系为醛与羟基取代基的对映选择性亨利反应提供了一种方法（见图）。

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《Chemistry: A European journal》 |2011年第4期|共4页
作者
Lai G.; Guo F.; Zheng Y.; Fang Y.; Song H.; Xu K.; Wang S.; Zha Z.; Wang Z.;
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正文语种 eng
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关键词
amines; anticancer agents; asymmetric synthesis; Henry reactions; water chemistry;

机译：胺类;抗癌剂;不对称合成;亨利反应;水化学;

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专利

1. Highly Enantioselective Henry Reactions in Water Catalyzed by a Copper Tertiary Amine Complex and Applied in the Synthesis of (S)-N-trans-Feruloyl Octopamine [J] . Guoyin Lai Fengfeng Guo Yueqin Zheng Yang Fang Haigang Song Kun Xu Dr. Sujing Wang Dr. Zhenggen Zha, Prof. Dr. Zhiyong Wang Chemistry - A European Journal . 2011,第4期

机译：铜叔胺配合物催化的水中高对映选择性亨利反应及其在合成（S）-N-反式-Fe-Froloylyl Octopamine中的应用
2. Highly enantioselective aza-henry reaction of ketimines catalyzed by a chiral bifunctional thiourea-tertiary amine derived from quinine [J] . Fang Yanhong, Lu Ning, Wei Zhonglin, Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2018,第50期

机译：通过奎宁衍生的手性双官能硫脲胺催化的酮致丙氨酸高度映射性Aza-Henry反应
3. Highly enantioselective Henry reactions of aromatic aldehydes catalyzed by an amino alcohol-copper(II) complex [J] . Qin D.-D., Lai W.-H., Hu D., Chemistry: A European journal . 2012,第34期

机译：氨基醇-铜（II）配合物催化的芳香醛的高对映选择性亨利反应
4. Enantioselective Synthesis of N-Aryl Amines and Diamines through Copper-Catalyzed Hydroamination of Alkenes [C] . Saki Ichikawa, Shaolin Zhu, Stephen L. Buchwald 日本化学会春季年会講演予稿集 . 2018

机译：通过烯烃铜催化的水聚酰胺对N-芳基胺和二胺的对映选择性合成
5. Copper-catalyzed enantioselective synthesis of tertiary and all-carbon quaternary stereogenic centers through conjugate addition of dialkylzinc reagents to nitroalkenes. [D] . Mampreian, Dawn Marie. 2005

机译：通过将二烷基锌试剂共轭添加到硝基烯烃中，铜催化的叔碳和全碳四元立体异构中心的对映选择性合成。
6. Enantioselective Synthesis of Homoallylic Amines through Reactions of (Pinacolato)allylborons with Aryl- Heteroaryl- Alkyl- or Alkene-Substituted Aldimines Catalyzed by Chiral C1-Symmetric NHC–Cu Complexes [O] . Erika M. Vieira, Marc L. Snapper, Amir H. Hoveyda -1

机译：通过与芳基 - 杂芳基烷基 - 或链烯的取代醛亚胺催化（频哪醇）allylborons手性C1-对称NHC - 铜配合物的反应高烯丙基胺的对映选择性合成
7. Highly Enantioselective Henry Reactions of Aromatic Aldehydes Catalyzed by an Amino Alcohol-Copper(II) Complex [O] . Qin Dan-Dan, Lai Wen-Han, Hu Di, 2012

机译：氨基醇-铜（II）配合物催化的芳香醛的高对映选择性亨利反应

Highly enantioselective henry reactions in water catalyzed by a copper tertiary amine complex and applied in the synthesis of (S)-N-trans-feruloyl octopamine

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