Isolated supramolecular [Ru(bpy)_3]-viologen-[Ru(bpy)_3] complexes with trapped CB[7,8] and photoinduced electron-transfer study in nonaqueous solution

Monhaphol T.K.; Andersson S.; Sun L.

首页> 外文期刊>Chemistry: A European journal >Isolated supramolecular [Ru(bpy)_3]-viologen-[Ru(bpy)_3] complexes with trapped CB[7,8] and photoinduced electron-transfer study in nonaqueous solution

【24h】

Isolated supramolecular [Ru(bpy)_3]-viologen-[Ru(bpy)_3] complexes with trapped CB[7,8] and photoinduced electron-transfer study in nonaqueous solution

机译：分离的超分子[Ru（bpy）_3]-紫精-[Ru（bpy）_3]配合物与捕获的CB [7,8]配合物在非水溶液中的光诱导电子转移研究

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The synthesis of two supramolecular diruthenium complexes, 1?CB[7] and 1?CB[8] (CB[n]=cucurbit[n]uril), which contain the respective host CB[7] and CB[8], were synthesized and isolated. In the case of host CB[8], the desired supramolecular complex was obtained by utilizing dihydroxynapthalene as a template during the synthesis. The ~1H NMR spectra, electrochemistry, and photochemistry of these supramolecular complexes were performed in nonaqueous solution. The results show that both CB[7,8] hosts mainly bind to the linker part in solution in acetonitrile. This binding also lowers the oxidation potential of the ruthenium metal center and hinders the quenching effect by the viologen moiety. It has also been shown that external methylviologen can be included into 1?CB[8]. Analysis with NMR spectroscopy, electrochemistry, and photochemistry clearly shows a viologen radical dimer formation between the bound viologen and free methylviologen, thereby showing that the unique abilities of the CB[8] host can be utilized even in nonaqueous solution.

机译：合成了两个超分子二钌配合物1？CB [7]和1？CB [8]（CB [n] = cucurbit [n] uril），它们分别包含主体CB [7]和CB [8]。合成和分离。对于宿主CB [8]，通过在合成过程中以二羟基萘为模板获得所需的超分子复合物。这些超分子配合物的〜1H NMR光谱，电化学和光化学在非水溶液中进行。结果表明，两种CB [7,8]主体均主要与乙腈溶液中的接头部分结合。这种结合还降低了钌金属中心的氧化电势并阻碍了紫精部分的猝灭作用。还表明，外部甲基紫精可以包含在1？CB中[8]。 NMR光谱，电化学和光化学分析清楚地表明，在结合的紫精和游离甲基紫精之间形成了紫精自由基二聚体，从而表明CB [8]主体的独特能力甚至可以在非水溶液中使用。

著录项

来源
《Chemistry: A European journal》 |2011年第41期|共9页
作者
Monhaphol T.K.; Andersson S.; Sun L.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词
cucurbit8uril; electron transfer; ruthenium; supramolecular chemistry; viologen;

机译：葫芦[8]脲;电子转移;钌;超分子化学;紫精;

相似文献

外文文献
中文文献
专利

1. Isolated supramolecular [Ru(bpy)_3]-viologen-[Ru(bpy)_3] complexes with trapped CB[7,8] and photoinduced electron-transfer study in nonaqueous solution [J] . Monhaphol T.K., Andersson S., Sun L. Chemistry: A European journal . 2011,第41期

机译：分离的超分子[Ru（bpy）_3]-紫精-[Ru（bpy）_3]配合物与捕获的CB [7,8]配合物在非水溶液中的光诱导电子转移研究
2. The synthesis and electrochemical behavior of ruthenium(III) bipyridine complexes: [Ru(dcbpy)Cl-4](-) (dcbpy-4,4 '-dicarboxylic acid-2,2 '-bipyridine) and [Ru(bpy)Cl3L] (L = CH3OH, PPh3, 4,4 '-bpy, CH3CN) [J] . Eskelinen E, Da Costa P, Haukka M Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry . 2005,第2期

机译：钌（III）联吡啶配合物的合成和电化学行为：[Ru（dcbpy）Cl-4]（-）（dcbpy-4,4'-di羧酸-2,2'-联吡啶）和[Ru（bpy）Cl3L ]（L = CH3OH，PPh3、4,4'-bpy，CH3CN）
3. Efficient microwave-assisted synthesis and characterization of key ruthenium(II) polypyridyl complexes [Ru(bpy)(3)](PF6)(2), [Ru(phen)(3)](PF6)(2), [Ru(bpy)(2)(phen)](PF6)(2) and [Ru(phen)(2)(bpy)](PF6)(2) [J] . Luis Ena T., Ball Graham E., Gilbert Alyssa, Journal of Coordination Chemistry . 2016,第11a13期

机译：有效的微波辅助合成和表征关键钌（II）聚吡啶配合物[Ru（bpy）（3）]（PF6）（2），[Ru（phen）（3）]（PF6）（2），[Ru（ bpy）（2）（phen）]（PF6）（2）和[Ru（phen）（2）（bpy）]（PF6）（2）
4. Ru(bpy)2(pbn)~(2+)およびRu(bpy)2(bpp)~(2+)の触媒反応機構に関する理論研究 [C] . 寺本玲奈, 名取圭紀, 北河康隆日本化学会春季年会講演予稿集 . 2018

机译：Ru（BPY）2（PBN）至（2+）和Ru（BPY）2（BPP）至（2+）催化反应机制。
5. Synthesis and Characterization of [Ru(tpyOH)(bpy)(H2O)][OTf]2 (tpyOH = 4′-Hydroxy-2,2’:6′, 2″- Terpyridine, Bpy = 2,2′-Bipyridine) for Water Oxidation Catalysis [D] . Isaacs, Diane Pearl. 2019

机译：[Ru（TPYOH）（BPY）（H2O）] [otf] 2（TPYOH = 4'-羟基-2,2'：6'，2“ - Terpyridine，BPy = 2,2'- Bi吡啶）的合成与表征用于水氧化催化
6. Accurate yet Feasible Computations of Resonance Raman Spectra for Metal Complexes in Solution: Ru(bpy)32+ as a Case Study [O] . Alberto Baiardi, Camille Latouche, Julien Bloino, -1

机译：溶液中金属配合物的共振拉曼光谱的准确而可行的计算：Ru（bpy）3 2+作为案例研究
7. Photoinduced Electron Transfer in an Anthraquinone–[Ru(bpy)₃]²⁺ –Oligotriarylamine–[Ru(bpy)₃]²⁺–Anthraquinone Pentad [O] . Bonn, Annabell G., Yushchenko, Oleksandr, Vauthey, Eric, 2016

机译：蒽醌– [Ru（bpy）_{3 ] ^{2 + –寡三芳胺– [Ru（bpy）_{3 ] ^{中的光诱导电子转移2 + -蒽醌五角}}}}
8. Laser Flash Photolysis Study of Magnetic Field Effects in Photoinduced ElectronTransfer between Ru(bpy)3(2+) and N,N'-dimethylviologen in Micellar Solutions [R] . Turro, N. J., Khudyakov, I. V., Gopidas, K. R. 1992

机译：激光闪光光解研究光诱导电子转移Ru（bpy）3（2+）与N，N'-二甲基紫精在胶束溶液中的磁场效应

Isolated supramolecular [Ru(bpy)_3]-viologen-[Ru(bpy)_3] complexes with trapped CB[7,8] and photoinduced electron-transfer study in nonaqueous solution

摘要

著录项

相似文献

相关主题

期刊订阅