Organometallic complexes in supported ionic-liquid phase (SILP) catalysts: A PHIP NMR spectroscopy study

Gong Q.; Klankermayer J.; Blümich B.

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Organometallic complexes in supported ionic-liquid phase (SILP) catalysts: A PHIP NMR spectroscopy study

机译：负载离子液体（SILP）催化剂中的有机金属络合物：PHIP NMR光谱研究

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para-Hydrogen induced polarization (PHIP) NMR spectroscopy emerges as an efficient and robust method for on-line monitoring of gas-phase hydrogenation reactions. Here we report detailed investigations of supported ionic liquid phase (SILP) catalysts in a continuous gas-phase hydrogenation of propene with PHIP NMR spectroscopy. A relocation of the rhodium complex in the thin layer of ionic liquid in the SILP catalyst at the initial stage of the propene hydrogenation is demonstrated. PHIP NMR spectroscopy can provide profound insight into the evolution of SILP catalysts during hydrogenation reactions.

机译：对氢诱导极化（PHIP）NMR光谱法是一种在线监测气相加氢反应的有效而可靠的方法。在这里，我们报告通过PHIP NMR光谱对丙烯进行连续气相加氢的负载型离子液体（SILP）催化剂的详细研究。在丙烯加氢的初始阶段，证明了铑配合物在SILP催化剂中离子液体薄层中的重定位。 PHIP NMR光谱可以为加氢反应期间SILP催化剂的演变提供深刻的见解。

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《Chemistry: A European journal》 |2011年第49期|共5页
作者
Gong Q.; Klankermayer J.; Blümich B.;
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正文语种 eng
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catalytic hydrogenation; gas-phase reactions; ionic liquids; NMR spectroscopy; rhodium complexes;

机译：催化加氢气相反应离子液体NMR光谱铑配合物;

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1. Organometallic complexes in supported ionic-liquid phase (SILP) catalysts: A PHIP NMR spectroscopy study [J] . Gong Q., Klankermayer J., Blümich B. Chemistry: A European journal . 2011,第49期

机译：负载离子液体（SILP）催化剂中的有机金属络合物：PHIP NMR光谱研究
2. SUPPORTED ORGANOMETALLIC COMPLEXES .8. CHEMISTRY IN INTERPHASES - CHEMICAL EXCHANGE IN A POLYSILOXANE-BOUND CHLOROHYDRIDOTRIS(ETHER-PHOSPHINE)RUTHENIUM(II) COMPLEX - AN INVESTIGATION BY SOLID-STATE NMR SPECTROSCOPY [J] . Lindner E., Schneller T., Mayer HA., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1995,第22期

机译：支持的有机复合物.8。界面化学-聚硅氧烷键合氯代（醚膦）R（II）络合物的化学交换-固态NMR光谱法的研究
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机译：支持的有机金属配合物。 XXVI-通过动态固态，悬浮态和氘核NMR光谱研究硅氧烷基无机-有机杂化聚合物
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机译：离子液体催化剂的高温NMR研究
5. Ultra-wideline solid-state NMR spectroscopy and its application in characterizing inorganic and organometallic complexes. [D] . Tang, Joel A. 2008

机译：超宽线固态NMR光谱及其在表征无机和有机金属配合物中的应用。
6. Reactive surface organometallic complexes observed using dynamic nuclear polarization surface enhanced NMR spectroscopy [O] . Eva Pump, Jasmine Viger-Gravel, Edy Abou-Hamad, 2017

机译：使用动态核极化表面增强NMR光谱观察到的反应性表面有机金属配合物
7. Organometallic Synthesis of Bimetallic Cobalt‐Rhodium Nanoparticles in Supported Ionic Liquid Phases (Co x Rh 100− x @SILP) as Catalysts for the Selective Hydrogenation of Multifunctional Aromatic Substrates [O] . Simon Rengshausen, Casey Van Stappen, Natalia Levin, 2020

机译：支持离子液相中的双金属钴 - 铑纳米粒子的有机金属合成（CO X RH 100- x @SILP）作为多官能芳族基材选择性氢化的催化剂
8. Fundamental studies of supported bimetallic catalysts by NMR spectroscopy [R] . Savargaonkar, N. 1996

机译：核磁共振光谱法研究负载双金属催化剂的基础研究

Organometallic complexes in supported ionic-liquid phase (SILP) catalysts: A PHIP NMR spectroscopy study

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