Activation of BaTaO _2N photocatalyst for enhanced non-sacrificial hydrogen evolution from water under visible light by forming a solid solution with BaZrO _3

Matoba T.; Maeda K.; Domen K.

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Activation of BaTaO _2N photocatalyst for enhanced non-sacrificial hydrogen evolution from water under visible light by forming a solid solution with BaZrO _3

机译：通过与BaZrO _3形成固溶体，活化BaTaO _2N光催化剂以增强可见光下水的非牺牲氢释放

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No sacrifice needed! Activation of perovskite-type BaTaO _2N (band gap: 1.8-1.9 eV) to improve photocatalytic activity for non-sacrificial H _2 evolution from water under visible light (λ>420 nm) was achieved by forming a solid solution with BaZrO _3, improving the performance six- to ninefold (see figure). The improvement is attributable to the increased driving force for the redox reactions and the reduced density of defects, which minimizes the undesirable electron-hole recombination.

机译：无需牺牲！通过与BaZrO _3形成固溶体，实现了钙钛矿型BaTaO _2N（带隙：1.8-1.9 eV）的活化，以改善可见光（λ> 420 nm）下非牺牲性H _2从水中析出的光催化活性。性能提高了六到九倍（见图）。改善归因于氧化还原反应的驱动力增加和缺陷密度降低，这使不良的电子-空穴复合最小化。

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《Chemistry: A European journal》 |2011年第52期|共5页
作者
Matoba T.; Maeda K.; Domen K.;
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正文语种 eng
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energy conversion; heterogeneous catalysis; photolysis; semiconductors; water splitting;

机译：能量转化;非均相催化;光解;半导体;水分解;

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1. Activation of BaTaO _2N photocatalyst for enhanced non-sacrificial hydrogen evolution from water under visible light by forming a solid solution with BaZrO _3 [J] . Matoba T., Maeda K., Domen K. Chemistry: A European journal . 2011,第52期

机译：通过与BaZrO _3形成固溶体，活化BaTaO _2N光催化剂以增强可见光下水的非牺牲氢释放
2. Water Oxidation Using a Particulate BaZrO3-BaTaO2N Solid-Solution Photocatalyst That Operates under a Wide Range of Visible Light [J] . Kazuhiko Maeda, Kazunari Domen Angewandte Chemie . 2012,第39期

机译：使用在宽可见光范围内运行的颗粒状BaZrO3-BaTaO2N固溶光催化剂进行水氧化
3. Preparation of BaZrO_3-BaTaO_2N solid solutions and the photocatalytic activities for water reduction and oxidation under visible light [J] . Kazuhiko Maeda, Kazunari Domen Journal of Catalysis . 2014,第Null期

机译：BaZrO_3-BaTaO_2N固溶体的制备及可见光下水还原和氧化的光催化活性
4. Synthesis of novel photocatalysts based on CD_(1-X)Mn_XS solid solution for hydrogen evolution under visible light irradiation [C] . K. O. Potapenko, A. Yu. Kurenkova, S. V. Cherepanova, All-Russian Scientific School-Conference for Young Scientists . 2020

机译：基于CD_（1-X）Mn_xS固溶体的新型光催化剂在可见光照射下的氢气进化中的固体溶液
5. Synthesis and photochemical study of N-doped mixed oxide solid solution photocatalyst for hydrogen production under visible light irradiation. [D] . Leswifi, Taile Y. 2014

机译：可见光照射下制氢用氮掺杂混合氧化物固溶光催化剂的合成及光化学研究。
6. An artificial photosynthesis anode electrode composed of a nanoparticulate photocatalyst film in a visible light responsive GaN-ZnO solid solution system [O] . Yoshihiko Imanaka, Toshihisa Anazawa, Toshio Manabe, -1

机译：在可见光响应型GaN-ZnO固溶体系中由纳米颗粒光催化剂膜组成的人工光合作用阳极
7. Preparation of BaZrO3–BaTaO2N solid solutions and the photocatalytic activities for water reduction and oxidation under visible light [O] . Kazuhiko Maeda, Kazunari Domen 2014

机译：Bazro3-Batao2N固体溶液的制备和可见光下的水还原和氧化的光催化活性

Activation of BaTaO _2N photocatalyst for enhanced non-sacrificial hydrogen evolution from water under visible light by forming a solid solution with BaZrO _3

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