Structures and energetics of the tert-butyl cation: The final answer or a never-ending story?

Feng H.; Sun W.; Xie Y.; Schaefer III H.F.

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Structures and energetics of the tert-butyl cation: The final answer or a never-ending story?

机译：叔丁基阳离子的结构和能量：最终答案还是永无止境的故事？

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Not C_(3v), not C_(3h), but C_s symmetry! High-level theory resolves the controversy concerning the equilibrium geometry of the tert-butyl cation (see figure). However, many mysteries remain.

机译：不是C_（3v），不是C_（3h），而是C_s对称！高级理论解决了有关叔丁基阳离子平衡几何学的争论（见图）。但是，仍然存在许多谜团。

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《Chemistry: A European journal》 |2011年第38期|共4页
作者
Feng H.; Sun W.; Xie Y.; Schaefer III H.F.;
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正文语种 eng
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carbocations; organic cations; physical organic chemistry; tert-butyl;

机译：碳阳离子;有机阳离子;物理有机化学;叔丁基;

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Structures and energetics of the tert-butyl cation: The final answer or a never-ending story?

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