Zwitterionic and anionic multinuclear pentacoordinate silicon(IV) complexes with bridging (R,R)-tartrato(4-) ligands and SiO _5 skeletons: Synthesis and reactivity in aqueous solution

Theis B.; Wei? J.; Lippert W.P.; Bertermann R.; Burschka C.; Tacke R.

首页> 外文期刊>Chemistry: A European journal >Zwitterionic and anionic multinuclear pentacoordinate silicon(IV) complexes with bridging (R,R)-tartrato(4-) ligands and SiO _5 skeletons: Synthesis and reactivity in aqueous solution

【24h】

Zwitterionic and anionic multinuclear pentacoordinate silicon(IV) complexes with bridging (R,R)-tartrato(4-) ligands and SiO _5 skeletons: Synthesis and reactivity in aqueous solution

机译：具有桥联（R，R）-酒石（4-）配体和SiO _5骨架的两性离子和阴离子多核五配位硅（IV）配合物：水溶液中的合成和反应性

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Two nutrients in one molecule: A zwitterionic λ ~5Si, λ ~5Si′-disilicate (1) was synthesized and characterized. It contains ligands that exclusively derive from natural products ((R,R)-tartaric acid, choline). Hydrolysis of 1 yields 2, which shows a remarkable kinetic stability in water. Upon dissolution of 1 and 2 in water, the nutrients choline and orthosilicic acid are formed by hydrolysis

机译：一分子中包含两种营养素：两性离子λ〜5Si，λ〜5Si'-二硅酸盐（1）并进行了表征。它包含专门来自天然产物（（R，R）-酒石酸，胆碱）的配体。 1的水解产生2，在水中显示出显着的动力学稳定性。将1和2溶解在水中后，营养物质胆碱和原硅酸通过水解形成

著录项

来源
《Chemistry: A European journal》 |2012年第8期|共5页
作者
Theis B.; Wei? J.; Lippert W.P.; Bertermann R.; Burschka C.; Tacke R.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词
bioinorganic chemistry; choline; pentacoordination; silicic acid; silicon;

机译：生物无机化学;胆碱;五配位;硅酸;硅;

相似文献

外文文献
中文文献
专利

1. Zwitterionic and anionic multinuclear pentacoordinate silicon(IV) complexes with bridging (R,R)-tartrato(4-) ligands and SiO _5 skeletons: Synthesis and reactivity in aqueous solution [J] . Theis B., Wei? J., Lippert W.P., Chemistry: A European journal . 2012,第8期

机译：具有桥联（R，R）-酒石（4-）配体和SiO _5骨架的两性离子和阴离子多核五配位硅（IV）配合物：水溶液中的合成和反应性
2. Neutral Pentacoordinate Silicon(IV) Complexes with a Tridentate Dianionic O,N,O or N,N,O Ligand, an Anionic PhX Ligand (X = O, S, Se), and a Phenyl Group: Synthesis and Structural Characterization in the Solid State and in Solution [J] . J?rg Wei?, Bastian Theis, Johannes A. Baus, Zeitschrift fur Anorganische und Allgemeine Chemie . 2014,第2期

机译：具有三齿双阳离子O，N，O或N，N，O配体，阴离子PhX配体（X = O，S，Se）和苯基的中性五配位硅（IV）配合物：固体中的合成和结构表征状态和解决方案
3. Neutral Hexacoordinate Silicon(IV) Complexes with an SiSO3NC Skeleton and a Neutral Pentacoordinate Silicon(IV) Complex Containing a Trianionic Tetradentate O,N,O,O Ligand [J] . Metz S, Burschka C, Tacke R Organometallics . 2009,第7期

机译：具有SiSO3NC骨架的中性六配位硅（IV）配合物和包含三阴离子四齿O，N，O，O配体的中性五配位硅（IV）配合物
4. Syntheses and Reactivities of NCN-Bridged Multinuclear Ruthenium Complexes with Arene Ligands [C] . Makoto Imaji, Yoshiaki Tanabe, Yuichiro Mutoh Symposium on Organometallic Chemistry . 2007

机译：用芳烃配体的NCN-桥接多核钌配合物的合成和反应性
5. Synthesis, structure and reactivity of titanium(IV) and titanium(II) complexes supported by proximally bridged p-t-butylcalix[4]arene ligands. [D] . Ozerov, Oleg Viktorovich. 2000

机译：近端桥对叔丁基杯[4]芳烃配体支撑的钛（IV）和钛（II）配合物的合成，结构和反应活性。
6. Heteropentanuclear Oxalato-Bridged nd–4f (n=4 5) Metal Complexes with NO Ligand: Synthesis Crystal Structures Aqueous Stability and Antiproliferative Activity [O] . Dr. Paul-Steffen Kuhn, B. Sc. Laura Cremer, Dr. Anatolie Gavriluta, -1

机译：杂配单核草酸酯桥联的nd–4f（n = 45）无配体的金属配合物：合成晶体结构水稳定性和抗增殖活性
7. Neutral Hexa- and Pentacoordinate Silicon(IV) Complexes with SiO6 and SiO4N Skeletons [O] . -1

机译：中性Hexa-和五坐标硅（IV）配合物，SiO6和SiO 4N骨架

Zwitterionic and anionic multinuclear pentacoordinate silicon(IV) complexes with bridging (R,R)-tartrato(4-) ligands and SiO _5 skeletons: Synthesis and reactivity in aqueous solution

摘要

著录项

相似文献

相关主题

期刊订阅