A moisture- and air-stable cationic ruthenium complex as catalyst for highly atom-economical stereo- and regioselective vinylation of azoles

Das U.K.; Bhattacharjee M.

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A moisture- and air-stable cationic ruthenium complex as catalyst for highly atom-economical stereo- and regioselective vinylation of azoles

机译：水分稳定和空气稳定的阳离子钌络合物，可作为催化剂，高度经济地进行唑的立体和区域选择性乙烯基化

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Vinylation of azoles: The cationic Ru ~(II) complex, [RuCl(PPh _3)(dppe)(CH _3CN) _2][BPh _4], is an efficient catalyst for regio- and stereoselective vinylation of azoles by alkynes (dppe=diphenylphosphinoethane; see scheme). Only 0.5 mol % of the complex is required and the reactions do not require stringent exclusion of moisture and air.

机译：唑类的乙烯基化：阳离子Ru〜（II）络合物[RuCl（PPh _3）（dppe）（CH _3CN）_2] [BPh _4]是有效的催化剂，可通过炔烃将唑类进行区域和立体选择性乙烯基化（dppe =二苯基膦乙烷;参见方案）。仅需要0.5mol％的配合物，并且反应不需要严格排除水分和空气。

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《Chemistry: A European journal》 |2012年第17期|共4页
作者
Das U.K.; Bhattacharjee M.;
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正文语种 eng
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关键词
alkynes; azoles; catalysis; ruthenium; vinylation;

机译：炔烃;唑类;催化;钌;乙烯基化;

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1. A moisture- and air-stable cationic ruthenium complex as catalyst for highly atom-economical stereo- and regioselective vinylation of azoles [J] . Das U.K., Bhattacharjee M. Chemistry: A European journal . 2012,第17期

机译：水分稳定和空气稳定的阳离子钌络合物，可作为催化剂，高度经济地进行唑的立体和区域选择性乙烯基化
2. A Robust, Moisture- and Air-Stable Phosphine Mono-Ylide Palladacycle Precatalyst: A Simple and Highly Efficient System for Mizoroki-Heck Reactions [J] . Seyyed Javad Sabounchei, Mohsen Ahmadi, Tayebeh Azizi, Synlett . 2014,第3期

机译：稳健，耐潮和耐空气的磷化氢一单环Palladacycle预催化剂：一种简单高效的Mizoroki-Heck反应体系
3. Strong Lewis acid air-stable cationic titanocene perfluoroalkyl(aryl)sulfonate complexes as highly efficient and recyclable catalysts for C–C bond forming reactions? [J] . Ningbo Li, Jinying Wang, Xiaohong Zhang, Dalton transactions: An international journal of inorganic chemistry . 2014,第30期

机译：强路易斯酸空气稳定型阳离子钛茂全氟烷基（芳基）磺酸盐配合物，可作为可催化的C–C键形成反应的催化剂吗？
4. Highly Active, Air-Stable Combinatorial Catalysts for the Cross-Coupling of Aryl Chlorides: The First Homogeneous Combinatorial Catalysts for Industrial Applications [C] . George Y. Li Combinatorial Approaches for New Materials Discovery . 2002

机译：用于芳基氯化物交叉偶联的高活性，空气稳定的组合催化剂：首个用于工业应用的均相组合催化剂
5. Ruthenium Phosphonium Alkylidene Complexes: From Decomposition to Tunable Highly Active Olefin Metathesis Catalysts. [D] . Leitao, Erin Michaela. 2011

机译：钌Ph亚烷基络合物：从分解到可调节的高活性烯烃复分解催化剂。
6. Regioselective Intermolecular Coupling Reaction of Arylketones and Alkenes Involving C-H Bond Activation Catalyzed by an In-Situ Formed Cationic Ruthenium-Hydride Complex [O] . Chae S. Yi, Do W. Lee -1

机译：arylketones和烯烃通过原位形成的阳离子钌氢化物络合物涉及C-H键活化催化的区域选择性分子间偶联反应
7. Self-supported thiourea-palladium complexes: Highly air-stable and recyclable catalysts for the Suzuki reaction in neat water [O] . Chen W, Li R, Wu Y, 2006

机译：自支撑的硫脲-钯配合物：纯净水中的铃木反应具有高度空气稳定性和可回收性的催化剂

A moisture- and air-stable cationic ruthenium complex as catalyst for highly atom-economical stereo- and regioselective vinylation of azoles

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