Telomerisation of buta-1,3-diene and methanol: Superiority of chromanyl-type phosphines in the dow process for the industrial production of 1-MOD

Tschan M.J.-L.; Launay H.; Hagen H.; Benet-Buchholz J.; Van Leeuwen P.W.N.M.

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Telomerisation of buta-1,3-diene and methanol: Superiority of chromanyl-type phosphines in the dow process for the industrial production of 1-MOD

机译：1,3-丁二烯和甲醇的端粒化：苯并二氢吡喃型膦在工业生产1-MOD的陶氏工艺中的优越性

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Butadiene and methanol were telomerised in the presence of palladium catalysts with ligands containing 8-diphenylphosphinochromane-like substituents at phosphorus. MonoXantphos and monoSPANphos afforded the most active, stable and selective catalysts known to date under commercially relevant production conditions for 1-methoxyocta-2,7-diene, the precursor to oct-1-ene.

机译：丁二烯和甲醇在钯催化剂存在下进行端粒化，所述钯催化剂的配位体在磷中含有类似8-二苯基膦基铬烷的取代基。 MonoXantphos和monoSPANphos提供了迄今在商业上相关的生产条件下已知的最活跃，稳定和选择性的催化剂，即1-甲氧基辛基-2,7-二烯（辛烯-1-烯的前体）。

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《Chemistry: A European journal》 |2011年第32期|共7页
作者
Tschan M.J.-L.; Launay H.; Hagen H.; Benet-Buchholz J.; Van Leeuwen P.W.N.M.;
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正文语种 eng
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关键词
carbenes; ligand design; palladium; phosphane ligands; telomerisation;

机译：卡宾;配体设计;钯;膦配体;端粒化;

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1. Telomerisation of Buta-1,3-diene and Methanol: Superiority of Chromanyl-Type Phosphines in the Dow Process for the Industrial Production of 1-MOD? [J] . Dr. Mathieu J.-L. Tschan, Dr. Hélène Launay, Dr. Henk Hagen, Chemistry - A European Journal . 2011,第32期

机译：Buta-1,3-二烯和甲醇的端聚反应：陶氏化学方法中工业上生产1-MOD ？的苯甲基型膦的优越性
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Telomerisation of buta-1,3-diene and methanol: Superiority of chromanyl-type phosphines in the dow process for the industrial production of 1-MOD

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