Transition-metal-free atropo-selective synthesis of biaryl compounds based on arynes

Leroux F.R.; Berthelot A.; Bonnafoux L.; Panossian A.; Colobert F.

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Transition-metal-free atropo-selective synthesis of biaryl compounds based on arynes

机译：基于芳烃的无过渡金属对偶合选择性芳族化合物的选择性合成

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摘要

A modular way towards biaryls: Highly enantioenriched biphenyls can be prepared based on a transition-metal-free aryl-aryl coupling followed by efficient desymmetrization or deracemization and chemoselective functionalization (see scheme).

机译：面向联芳基的模块化方法：可以基于无过渡金属的芳基-芳基偶合，然后进行有效的脱对称或脱氨和化学选择性官能化（参见方案），制备高度对映体富集的联苯。

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《Chemistry: A European journal》 |2012年第45期|共5页
作者
Leroux F.R.; Berthelot A.; Bonnafoux L.; Panossian A.; Colobert F.;
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正文语种 eng
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关键词
biaryls; chirality; selectivity; sulfoxide; synthetic methods;

机译：联芳基;手性;选择性;亚砜;合成方法;

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1. Transition-metal-free atropo-selective synthesis of biaryl compounds based on arynes [J] . Leroux F.R., Berthelot A., Bonnafoux L., Chemistry: A European journal . 2012,第45期

机译：基于芳烃的无过渡金属对偶合选择性芳族化合物的选择性合成
2. Synthesis of biaryls via palladium-catalyzed [2+2+2] cocyclization of arynes and diynes: Application to the synthesis of arylnaphthalene lignans [J] . Sato Y, Tamura T, Kinbara A, Advanced synthesis & catalysis . 2007,第4a5期

机译：通过芳烃和二炔的钯催化[2 + 2 + 2]共环化合成联芳基：在芳基萘木脂素的合成中的应用
3. Transition-Metal-Free Benzannulation of Tricarbonyl Derivatives with Arynes: Access to 1,3-Dinaphthol Precursors for the Synthesis of Rhodamine Dye Analogues [J] . Ghotekar Ganesh S., Shaikh Aslam C., Muthukrishnan M. The Journal of Organic Chemistry . 2019,第4期

机译：三羰基衍生物的无金属无金属苯胺与arynes：获得1,3-二甲胺前体的合成罗丹明染料类似物
4. Tandem Diels-Alder Reactions of Arynes: New Method for the Synthesis of Large Poly cyclic Aromatic Compounds and Nanographenes [C] . Diego Pena, Alejandro Criado, Dolores Perez European Symposium on Organic Chemistry . 2009

机译：Arynes的串联Diels-Alder反应：用于合成大聚环芳族化合物和纳米的新方法
5. Synthesis of Biaryl Compounds by Detellurative Coupling of Diaryl Ditellurides [D] . Abdo Alwani, Naif Yahya. 2020

机译：用二芳基二硫酸酯的脱果偶联来合成芳基化合物
6. Empowering Transition-Metal-Free Cascade Protocolfor the Green Synthesis of Biaryls and Alkynes [O] . PreetKamal Walia, Manoj Kumar, Vandana Bhalla, 2018

机译：增强无过渡金属级联协议用于绿色合成联芳基和炔烃
7. Transition-Metal-Free Heterobiaryl Synthesis via Aryne Coupling [O] . Tarak Saied, Catherine Demangeat, Armen Panossian, 2019

机译：通过Aryne偶联的过渡 - 无金属杂芳烃合成
8. Process for the Catalytic Synthesis of Biaryls and Polymers from Aryl Compounds. [R] . Smith, M. R., Maleczka, R. E. 2005

机译：从芳基化合物催化合成联芳基和聚合物的方法。

Transition-metal-free atropo-selective synthesis of biaryl compounds based on arynes

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