Tris(bispyrene-bipyridine)iron(II): A supramolecular bridge for the biofunctionalization of carbon nanotubes via π-stacking and pyrene/β-cyclodextrin host-guest interactions

Le Goff A.; Gorgy K.; Holzinger M.; Haddad R.; Zimmerman M.; Cosnier S.

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Tris(bispyrene-bipyridine)iron(II): A supramolecular bridge for the biofunctionalization of carbon nanotubes via π-stacking and pyrene/β-cyclodextrin host-guest interactions

机译：Tris（bispyrene-bipyridine）iron（II）：超分子桥，用于通过π堆积和pyr /β-环糊精与客体-客体的相互作用对碳纳米管进行生物功能化

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Bridging bio to nano: A simple procedure is reported to fabricate a biosensor by using the capacities of pyrene derivatives which are attached to nanotube sidewalls and to form host-guest complexes with β-cyclodextrins (see figure). A trisbipy iron(II) complex containing six pyrene groups was synthesized and attached to carbon nanotubes. β-Cyclodextrin-modified glucose oxidase was used as a model enzyme to form the pyrene/β- cyclodextrin inclusion complex, thus efficiently immobilizing the enzyme.

机译：将生物桥接到纳米：据报道，通过使用the衍生物的能力来制造生物传感器，该capacities与纳米管侧壁相连，并与β-环糊精形成客体-客体复合物（见图）。合成了包含六个pyr基的三联铁（II）配合物，并将其连接到碳纳米管。 β-环糊精修饰的葡萄糖氧化酶被用作模型酶以形成the /β-环糊精包合物，从而有效地固定了该酶。

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《Chemistry: A European journal》 |2011年第37期|共6页
作者
Le Goff A.; Gorgy K.; Holzinger M.; Haddad R.; Zimmerman M.; Cosnier S.;
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正文语种 eng
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biosensors; carbon nanotubes; cyclodextrins; electropolymerization; pi interactions;

机译：生物传感器;碳纳米管;环糊精;电聚合;π相互作用;

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1. Tris(bispyrene-bipyridine)iron(II): A supramolecular bridge for the biofunctionalization of carbon nanotubes via π-stacking and pyrene/β-cyclodextrin host-guest interactions [J] . Le Goff A., Gorgy K., Holzinger M., Chemistry: A European journal . 2011,第37期

机译：Tris（bispyrene-bipyridine）iron（II）：超分子桥，用于通过π堆积和pyr /β-环糊精与客体-客体的相互作用对碳纳米管进行生物功能化
2. Bridged-cyclodextrin supramolecular hydrogels: host-guest interaction between a cyclodextrin dimer and adamantyl substituted poly(acrylate)s [J] . Wang Jie, Xu Yisheng, Wang Yiming, RSC Advances . 2015,第57期

机译：桥联环糊精超分子水凝胶：环糊精二聚体与金刚烷基取代的聚丙烯酸酯之间的客体相互作用
3. Pyrene-adamantane-β-cyclodextrin: An efficient host-guest system for the biofunctionalization of SWGNT electrodes [J] . Raoudha Haddad, Michael Holzinger, Reynaldo Villalonga Carbon: An International Journal Sponsored by the American Carbon Society . 2011,第7期

机译：yr-金刚烷-β-环糊精：用于SWGNT电极生物功能化的高效宿主系统
4. Study on the Supramolecular Interaction of Dopamine With Carbon Nanotubes and β-Cyclodextrin Immovilized over a Carbon Paste Electrode [C] . M. Palomar-Pardave, G. Alarcon-Angeles, S. Corona Avendano, MES 26: Electrochemistry as a tool for sustainable development . 2011

机译：多巴胺与碳纳米管和固定在碳糊电极上的β-环糊精的超分子相互作用的研究
5. Supramolecular host-guest interactions of cyclodextrins and calixarenes with niobocene and vanadocene [D] . Morales Blanco, Alexis J. 2010

机译：环糊精和杯芳烃与新世代和钒二烯的超分子主客体相互作用
6. Supramolecular host-guest interaction of trityl-nitroxide biradicals with cyclodextrins: modulation of spin-spin interaction and redox sensitivity [O] . Xiaoli Tan, Yuguang Song, Huiqiang Liu, -1

机译：三苯甲基-硝基氧化物双自由基与环糊精的超分子宿主-客体相互作用：自旋-自旋相互作用和氧化还原敏感性的调节
7. π-Stacking attraction vs. electrostatic repulsion: competing supramolecular interactions in a tpphz-bridged Ru( ii )/Au( iii ) complex [O] . Sorsche, Dieter, Schaub, Markus, Heinemann, Frank W., 2016

机译：π堆积吸引与静电排斥：在tpphz桥接Ru（ii）/ Au（iii）络合物中竞争的超分子相互作用

Tris(bispyrene-bipyridine)iron(II): A supramolecular bridge for the biofunctionalization of carbon nanotubes via π-stacking and pyrene/β-cyclodextrin host-guest interactions

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