Tuning the electronic and spin complexity in organic-inorganic molecular hybrid compounds

Rabeah J.; St??er R.; Jiao H.; Troyanov S.I.; Radnik J.; Dwelk H.; Meisel M.; Brückner A.

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Tuning the electronic and spin complexity in organic-inorganic molecular hybrid compounds

机译：调节有机-无机分子杂化化合物的电子和自旋复杂性

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Caught by the cage: New vanadium phosphonate cages with a fluoride template inside and charge-compensating transition-metal cations outside were prepared in a simple way. The charge and ligand sphere of the cation govern its interaction with the cage and can be used to modify the magnetic and redox properties of the cage, which also depend on the anionic template (see figure).

机译：被笼子抓住：用一种简单的方法制备了新的膦酸钒钒笼子，里面有氟化物模板，外面有电荷补偿的过渡金属阳离子。阳离子的电荷和配体球决定了它与笼子的相互作用，可以用来修饰笼子的磁性和氧化还原特性，这也取决于阴离子模板（见图）。

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《Chemistry: A European journal》 |2012年第21期|共4页
作者
Rabeah J.; St??er R.; Jiao H.; Troyanov S.I.; Radnik J.; Dwelk H.; Meisel M.; Brückner A.;
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正文语种 eng
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关键词
cage compounds; electronic structure; EPR spectroscopy; organic-inorganic hybrid composites; vanadium;

机译：笼状化合物;电子结构;EPR光谱;有机-无机杂化复合材料;钒;

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1. Tuning the electronic and spin complexity in organic-inorganic molecular hybrid compounds [J] . Rabeah J., St??er R., Jiao H., Chemistry: A European journal . 2012,第21期

机译：调节有机-无机分子杂化化合物的电子和自旋复杂性
2. Hybrid Density Functional Theory (DFT) Study on Electronic States of Halogen-Substituted Organic-Inorganic Hybrid Compounds: Al-NTCDA [J] . Hiroto Tachikawa, Hiroshi Kawabata Japanese Journal of Applied Physics. Part 1, Regular Papers & Short Notes . 2005,第6A期

机译：卤素取代的有机-无机杂化化合物Al-NTCDA电子态的杂化密度泛函理论（DFT）研究
3. Spin-Polarized Electronic Transport through Ferromagnet/Organic-Inorganic Hybrid Perovskite Spinterfaces at Room Temperature [J] . Wang Kai, Yang Qin, Duan Jiashun, Advanced materials interfaces . 2019,第19期

机译：通过铁圆环/有机无机杂交钙钛矿间旋转偏振电子传输在室温下截止物
4. Molecular Organic-inorganic Layer Compounds as Electronic Functional Materials [C] . Peter Day International Conference on Physics of Emerging Functional Materials . 2010

机译：分子有机无机层化合物作为电子功能材料
5. Studies on the structures and properties of bimetallic uranium transition metal and hybrid organic-inorganic compounds. [D] . Yu, Yaqin. 2009

机译：双金属铀过渡金属和杂化有机-无机化合物的结构和性能研究。
6. Ti/Au Cathode for Electronic transport material-free organic-inorganic hybrid perovskite solar cells [O] . Tongfei Shi, Jian Chen, Jianqiang Zheng, -1

机译：Ti / Au阴极用于无电子传输材料的有机-无机混合钙钛矿太阳能电池
7. ((EDT-TTF-CONH2)6Re6Se8(CN)6, a Metallic Kagome-Type Organic-Inorganic Hybrid Compound: Electronic Instability, Molecular Motion, and Charge Localization [O] . -1

机译：（（EDT-TTF-CONH2）6 RE6SE8（CN）6，金属kagome型有机无机杂化化合物：电子不稳定，分子运动和充电定位

Tuning the electronic and spin complexity in organic-inorganic molecular hybrid compounds

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