• 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Chemistry: A European journal >Direct sp~3 C-H amination of nitrogen-containing benzoheterocycles mediated by visible-light-photoredox catalysts
【24h】

Direct sp~3 C-H amination of nitrogen-containing benzoheterocycles mediated by visible-light-photoredox catalysts

机译：可见光-光氧化还原催化剂介导的含氮苯并杂环直接sp〜3 C-H胺化

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

Visible-light-mediated direct sp~3 C-H amination of benzocyclic amines via α-aminoalkyl radicals by using photoredox catalysts is described here. The obtained N,N-acetals were also successfully applied for carbon-carbon bond forming reactions with carbon nucleophiles. The procedure is suitable for a late-stage modification of C-H bonds to C-C bonds. Amination sees the light: Visible-light-mediated direct sp3 C-H amination of benzocyclic amines via α-aminoalkyl radicals by using photoredox catalysts is described here (see scheme). The obtained N,N-acetals were also successfully applied for carbon-carbon bond-forming reactions with carbon nucleophiles. The procedure is suitable for a late-stage modification of C-H bonds to C-C bonds.
机译：本文描述了使用光氧化还原催化剂通过α-氨基烷基自由基对苯并环胺的可见光直接sp〜3 C-H胺化反应。所获得的N，N-缩醛也成功地用于与碳亲核试剂的碳-碳键形成反应。该程序适用于将C-H键后期修饰为C-C键的过程。胺化反应见光：本文描述了使用光氧化还原催化剂通过α-氨基烷基自由基进行的可见光介导的苯环胺的直接sp3 C-H胺化（参见方案）。所获得的N，N-缩醛也成功地用于与碳亲核试剂的碳-碳键形成反应。该程序适用于将C-H键后期修饰为C-C键的过程。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号