The catalytic ability of various transition metals in the direct functionalization of aromatic C-H bonds

Li H.; Sun C.-L.; Yu M.; Yu D.-G.; Li B.-J.; Shi Z.-J.

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The catalytic ability of various transition metals in the direct functionalization of aromatic C-H bonds

机译：各种过渡金属在芳族C-H键直接官能化中的催化能力

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From noble to normal: Many transition-metal complexes have shown a remarkable ability to catalyze the cross-coupling of aryl halides with arenes (see scheme). The formation of biaryls has thus been achieved using inexpensive, readily available, and sometimes nontoxic transition-metal complexes. Not only "noble" transition metals, but also many of the "normal" transition metals are able to promote the direct transformation of C-H bonds.

机译：从贵金属到普通金属：许多过渡金属络合物显示出显着的催化芳基卤化物与芳烃交叉偶联的能力（请参阅方案）。因此，已经使用廉价的，容易获得的，有时是无毒的过渡金属络合物实现了联芳基的形成。不仅“贵金属”过渡金属，而且许多“正常”过渡金属都能够促进C-H键的直接转化。

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《Chemistry: A European journal》 |2011年第13期|共5页
作者
Li H.; Sun C.-L.; Yu M.; Yu D.-G.; Li B.-J.; Shi Z.-J.;
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正文语种 eng
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关键词
aryl bromide; biaryls; C-H activation; cross-coupling; transition-metal catalysis;

机译：芳基溴化物;联芳基;C-H活化;交叉偶联;过渡金属催化;

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专利

1. The catalytic ability of various transition metals in the direct functionalization of aromatic C-H bonds [J] . Li H., Sun C.-L., Yu M., Chemistry: A European journal . 2011,第13期

机译：各种过渡金属在芳族C-H键直接官能化中的催化能力
2. Transition metal-catalyzed C-H bond functionalizations by the use of diverse directing groups [J] . Zhengkai Chen, Binjie Wang, Jitan Zhang Organic Chemistry Frontiers . 2015,第9期

机译：过渡金属催化的C-H键功能化通过使用不同的导向基团
3. Transition-metal-catalyzed synthesis of aromatic ketones via direct C-H bond activation [J] . PanC., JiaX., ChengJ. Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2012,第5期

机译：过渡金属催化的直接C-H键活化合成芳族酮
4. Catalytic Asymmetric C-H Functionalization by High-valent Group 9 Metals [C] . Tatsuhiko Yoshino 日本化学会春季年会講演予稿集 . 2018

机译：高价群9金属催化不对称C-H官能化
5. Transition Metal Mediated Non-directed C-H Functionalization [D] . Gair, Joseph J. 2018

机译：过渡金属介导的非定向C-H功能化
6. Insights into Directing Group Ability in Palladium-Catalyzed C-H Bond Functionalization [O] . Lopa V. Desai, Kara J. Stowers, Melanie S. Sanford -1

机译：钯催化的C-H键官能化中指导基团能力的见解
7. Sterically Directed Functionalization of Aromatic C-H Bonds: Selective Borylation Ortho to Cyano Groups in Arenes and Heterocycles [O] . -1

机译：芳族C-H键的空间上函数：选择性促进植物和杂环中的氰基
8. Direct Selective Acylation of an Unactivated C-H Bond in a Caged Hydrocarbon.Approach to Systems for C-H Bond Functionalization That Proceed Catalytically and Selectively at High Substrate Conversion [R] . Prosser-McCartha, C. M., Hill, C. L. 1990

机译：笼型烃中未活化C-H键的直接选择性酰化。用于C-H键官能化的系统，在高基质转化下催化和选择性地进行

The catalytic ability of various transition metals in the direct functionalization of aromatic C-H bonds

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