Palladium-catalyzed cross-coupling of unactivated alkenes with acrylates: Application to the synthesis of the C13-C21 fragment of palmerolide A

Wen Z.-K.; Xu Y.-H.; Loh T.-P.

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Palladium-catalyzed cross-coupling of unactivated alkenes with acrylates: Application to the synthesis of the C13-C21 fragment of palmerolide A

机译：钯催化未活化烯烃与丙烯酸酯的交叉偶联：在合成棕榈油内酯A的C13-C21片段中的应用

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Diene to meet: A palladium-catalyzed cross-coupling reaction between alkyl-substituted olefins and acrylates gives the corresponding butadienes in moderate yield and stereoselectivity. This atom-economical reaction, which forms C sp 2-C sp 2 bonds, tolerates a wide range of allylic and homoallylic alcohols, and acrylates (see scheme; TIPS =triisopropylsilyl). The methodology was applied to the synthesis of the C13-C21 fragment of palmerolide A.

机译：满足的二烯：烷基取代的烯烃与丙烯酸酯之间的钯催化交叉偶联反应以中等收率和立体选择性得到相应的丁二烯。形成C sp 2-C sp 2键的这种原子经济反应可耐受各种烯丙基和均烯丙基醇和丙烯酸酯（参见方案; TIPS =三异丙基甲硅烷基）。该方法应用于棕榈油内酯A的C13-C21片段的合成。

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《Chemistry: A European journal》 |2012年第42期|共4页
作者
Wen Z.-K.; Xu Y.-H.; Loh T.-P.;
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正文语种 eng
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关键词
butadienes; C-H bond functionalization; cross-coupling; palladium; palmerolide A;

机译：丁二烯;C-H键官能化;交叉偶联;钯;帕美洛利A;

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1. Palladium-catalyzed cross-coupling of unactivated alkenes with acrylates: Application to the synthesis of the C13-C21 fragment of palmerolide A [J] . Wen Z.-K., Xu Y.-H., Loh T.-P. Chemistry: A European journal . 2012,第42期

机译：钯催化未活化烯烃与丙烯酸酯的交叉偶联：在合成棕榈油内酯A的C13-C21片段中的应用
2. Synthesis of Alkyl Indium Reagents by Using Unactivated Alkyl Chlorides and Their Applications in Palladium-Catalyzed Cross-Coupling Reactions with Aryl Halides [J] . Bing-Zhi Chen, Man-Ling Zhi, Chuang-Xin Wang, Organic letters . 2018,第7期

机译：通过使用芳克催化芳基催化的烷基氯化物及其在钯催化的交叉偶联反应中的应用来合成烷基铟试剂
3. Umpolung with Sulfur Dioxide: Carbon-Carbon Cross-Coupling of Electron-Rich 1,3-Dienes and Alkenes; Application to the Enantioselective Synthesis of Long-Chain Polyketide Fragments [J] . Maris Turks, Claudia J. Exner, Cotinica Hamel, Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2009,第7期

机译：用二氧化硫进行的Ulpolung：富电子的1,3-二烯和烯烃的碳-碳交叉偶联;在长链聚酮化合物片段的对映选择性合成中的应用
4. Highly Stereoselective Synthesis with Polyborylated Reagents: Cross-coupling of 1,1.Diboryl-l-alkenes and Triple Aldehyde Addition of(Z)-l,2,3,4-Tetraboryl-2-butene [C] . Masaki Shimizu, Katsuhiro Shimono, Chihiro Nakamaki, Symposium on Organometallic Chemistry . 2004

机译：高度立体化合成具有聚合物化试剂：1,1.Diboryl-L-烯烃的交叉偶联和三重醛加入（Z）-L，2,3,4-四甲基-2-丁烯
5. Stereoselective synthesis of vinyl germanes and silanes. Applications of tris(trimethyl)germanes and silanes in palladium-catalyzed cross-coupling reactions. [D] . Wang, Zhizhong. 2005

机译：乙烯基锗烷和硅烷的立体选择性合成。三（三甲基）锗烷和硅烷在钯催化的交叉偶联反应中的应用。
6. Palladium-Catalyzed Carbocyclizations of Unactivated Alkyl Bromides with Alkenes Involving Auto-Tandem Catalysis [O] . Alexander R. O. Venning, Megan R. Kwiatkowski, Joan E. Roque Peña, -1

机译：钯催化未活化烷基溴化物与涉及自动串联催化的烯烃的碳环化反应
7. Palladium-catalyzed heteroallylation of unactivated alkenes – synthesis of citalopram [O] . Hewitt, J.F.M., Williams, L., Aggarwal, P., 2013

机译：钯催化的未活化烯烃的杂化 - 西酞普兰的合成

Palladium-catalyzed cross-coupling of unactivated alkenes with acrylates: Application to the synthesis of the C13-C21 fragment of palmerolide A

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