Metal-metal interaction and flexible motion of triple-decker polypyridyl platinum(II) and palladium(II) complexes

Kajitani Y.; Tsuge K.; Sasaki Y.; Kato M.

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Metal-metal interaction and flexible motion of triple-decker polypyridyl platinum(II) and palladium(II) complexes

机译：三层聚吡啶铂（II）和钯（II）配合物的金属-金属相互作用和柔性运动

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摘要

Triple-decker polypyridyl platinum(II) and palladium(II) complexes were prepared using an N,S-bridging ligand. In solution, tight stacking structures were observed at low temperatures, whereas flexible motion was observed at room temperature. These dynamic behaviors are reflected in the electronic absorption and NMR spectra of these complexes (see scheme).

机译：使用N，S桥联配体制备了三层聚吡啶基铂（II）和钯（II）配合物。在溶液中，在低温下观察到紧密的堆叠结构，而在室温下观察到柔性运动。这些动力学行为反映在这些配合物的电子吸收和NMR光谱中（请参见方案）。

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《Chemistry: A European journal》 |2012年第36期|共5页
作者
Kajitani Y.; Tsuge K.; Sasaki Y.; Kato M.;
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正文语种 eng
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fluxionality; metal-metal interactions; N; S ligands; palladium; platinum;

机译：通量;金属-金属相互作用;N;S配体;钯;铂;

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1. Metal-metal interaction and flexible motion of triple-decker polypyridyl platinum(II) and palladium(II) complexes [J] . Kajitani Y., Tsuge K., Sasaki Y., Chemistry: A European journal . 2012,第36期

机译：三层聚吡啶铂（II）和钯（II）配合物的金属-金属相互作用和柔性运动
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机译：1,1'-双（膦）茂金属（m = fe，ru）配体的钯（II）和铂（II）化合物具有金属-金属相互作用
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4. Dynamic Rotational Motions of Vaulted Chiral trans- Bis(salicylaldiminato)Pd(II) Complexes Bearing Rigid or Flexible Carbon Chain Linkers [C] . Masahiro Ikeshita, Takeshi Naota 日本化学会春季年会講演予稿集 . 2018

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Metal-metal interaction and flexible motion of triple-decker polypyridyl platinum(II) and palladium(II) complexes

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