Preparation of copper(I) pseudo-rotaxanes from bis-phosphine ligands

Mohankumar M.; Holler M.; Nierengarten J.-F.; Sauvage J.-P.

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Preparation of copper(I) pseudo-rotaxanes from bis-phosphine ligands

机译：由双膦配体制备铜（I）拟轮烷

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The preparation of heteroleptic Cu complexes from various 2,9-disubstituted-1,10-phenanthrolines(phen) and different bis-phosphine(PP) ligands was investigated. These heteroleptic complexes are found to be stable in CH _2Cl _2 solutions and no detectable ligand exchange reactions could be detected. The results also show that the CuI-mediated threading of all the bis-phosphine ligands through the macrocycle is effective. The X-ray crystal structure analysis of BF _4 proves the threading of the POP moiety through the macrocyclic phenanthroline ligand. The intramolecular face-to-face p p interaction between one phenyl ring of the POP ligand and the phenanthroline moiety induces a significant rocking of the POP ligand. The results also show that formation of the homoleptic bisphenanthroline Cu complex is prevented by the macrocyclic nature of the phenanthroline ligand.

机译：研究了由2,9-二取代-1,10-菲咯啉（phen）和不同的双膦（PP）配体制备的杂铜配合物。发现这些杂合配合物在CH _2Cl _2溶液中稳定，并且未检测到可检测到的配体交换反应。结果还表明，CuI介导的所有双膦配体穿过大环是有效的。 BF _4的X射线晶体结构分析证明POP部分穿过大环菲咯啉配体。 POP配体的一个苯环与菲咯啉部分之间的分子内面对面p p相互作用引起POP配体的明显摇动。结果还表明，菲咯啉配体的大环性质阻止了均双酚菲啉铜配合物的形成。

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《Chemistry: A European journal》 |2012年第39期|共4页
作者
Mohankumar M.; Holler M.; Nierengarten J.-F.; Sauvage J.-P.;
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正文语种 eng
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copper; macrocyclic ligands; phenanthroline; phosphine ligands; rotaxane;

机译：铜;大环配体;菲咯啉;膦配体;轮烷;

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1. Preparation of copper(I) pseudo-rotaxanes from bis-phosphine ligands [J] . Mohankumar M., Holler M., Nierengarten J.-F., Chemistry: A European journal . 2012,第39期

机译：由双膦配体制备铜（I）拟轮烷
2. Heteroleptic Copper(I) Complexes Prepared from Phenanthroline and Bis-Phosphine Ligands: Rationalization of the Photophysical and Electrochemical Properties [J] . Leoni Enrico, Mohanraj John, Holler Michel, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2018,第24期

机译：由菲咯啉和双叔膦配体制备的异致铜（I）配合物：光性和电化学性能的合理化
3. Electrophosphorescent homo- and heteroleptic copper(I) complexes prepared from various bis-phosphine ligands [J] . Omar Moudam, Adrien Kaeser, Beatrice Delavaux-Nicot, Chemical Communications . 2007,第29期

机译：由各种双膦配体制备的电致磷化均铜和杂铜（I）配合物
4. Structure of Copper Mixed Ligand Complex with Tetramethylethylenediamine as Primary Ligand by EXAFS [C] . Sharad Sharma, S. K. Joshi, V. K. Hinge, National Conference on Physics and Chemistry of Materials . 2019

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5. Dioxygen reactivity of synthetic analogues for the active site of heme-copper oxidases: Copper-ligand influences in iron(II)/copper(I)/oxygen chemistry. [D] . Kim, Eunsuk. 2005

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6. Complexes With Biologically Active Ligands. Part 2. Preparation ofCopper(II) Complexes of Positively-Charged Derivatives of Aminoglutethimide [O] . Claudiu T. Supuran 1996

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Preparation of copper(I) pseudo-rotaxanes from bis-phosphine ligands

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