Carbon monoxide assisted self-assembled platinum nanoparticles for catalytic asymmetric hydrogenation

Indra A.; Lahiri G.K.

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Carbon monoxide assisted self-assembled platinum nanoparticles for catalytic asymmetric hydrogenation

机译：一氧化碳辅助自组装铂纳米颗粒催化不对称加氢

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Pt NPs CO-operate: Pt nanorods (Pt NRs) have been developed by the self-assembly of uniformly distributed small Pt nanoparticles (Pt NPs, 1.8-2.4 nm), obtained from [Pt(cod)Cl _2] (cod=1,5-cyclooctadiene) in the presence of CO in non-aqueous medium. As-synthesized non-supported Pt NRs catalyze the asymmetric hydrogenation of methyl pyruvate and acetophenone to (R)-methyl lactate and (R)-1-phenyl ethanol, respectively (see scheme).

机译：Pt NPs合作：Pt纳米棒（Pt NRs）是通过自组装从[Pt（cod）Cl _2]（cod = 1）获得的均匀分布的小Pt纳米颗粒（Pt NPs，1.8-2.4 nm）自行开发的。（5-5-环辛二烯）在非水介质中在CO的存在下。合成后的非负载Pt NRs分别催化丙酮酸甲酯和苯乙酮的不对称氢化为（R）-乳酸甲酯和（R）-1-苯基乙醇（参见方案）。

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《Chemistry: A European journal》 |2012年第22期|共4页
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Indra A.; Lahiri G.K.;
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正文语种 eng
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asymmetric hydrogenation; carbon monoxide; nanoparticles; nanorods; self-assembly;

机译：不对称氢化一氧化碳纳米粒子纳米粒子自组装;

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1. Carbon monoxide assisted self-assembled platinum nanoparticles for catalytic asymmetric hydrogenation [J] . Indra A., Lahiri G.K. Chemistry: A European journal . 2012,第22期

机译：一氧化碳辅助自组装铂纳米颗粒催化不对称加氢
2. The Role of an Organic Cap in Nanoparticle Catalysis: Reversible Restructuring of Carbonaceous Material Controls Catalytic Activity of Platinum Nanoparticles for Ethylene Hydrogenation and Methanol Oxidation [J] . L. Robert Baker, Griffin Kennedy, James M. Krier Catalysis Letters . 2012,第11期

机译：有机帽在纳米粒子催化中的作用：含碳材料的可逆结构控制铂纳米粒子对乙烯加氢和甲醇氧化的催化活性
3. The Role of an Organic Cap in Nanoparticle Catalysis: Reversible Restructuring of Carbonaceous Material Controls Catalytic Activity of Platinum Nanoparticles for Ethylene Hydrogenation and Methanol Oxidation [J] . L. Robert Baker, Griffin Kennedy, James M. Krier, Catalysis Letters . 2012,第11期

机译：有机帽在纳米粒子催化中的作用：含碳材料的可逆结构控制铂纳米粒子对乙烯加氢和甲醇氧化的催化活性
4. Mesoporous carbon-supported β-Mo_2C for catalytic hydrogenation of carbon monoxide to mixed alcohols [C] . Ruijue Hu, Jianli Li, Xiaohong Zhang, International Workshop on Advances in Energy Science and Environment Engineering . 2018

机译：中孔碳负载β-MO_2C，用于催化氢化一氧化碳与混合醇
5. TRIOSMIUM CLUSTERS AS MODELS FOR INTERMEDIATES IN CATALYTIC CARBON MONOXIDE HYDROGENATION REACTIONS (METHYLENE, KETENE, INSERTION, PHOSPHIDO, PLATINUM). [D] . MORRISON, ERIC DANIEL. 1985

机译：三氧化锡簇作为催化碳一氧化碳加氢反应（亚甲基，丁烯，插入，磷，铂）中间体的模型。
6. Carbon Monoxide Promotes the Catalytic Hydrogenation on Metal Cluster Catalysts [O] . Ruixuan Qin, Pei Wang, Pengxin Liu, 2020

机译：一氧化碳促进金属簇催化剂上的催化氢化
7. The Accommodation Coefficients of Carbon Monoxide and Oxygen on Platinum during the Catalytic Oxidation of Carbon Monoxide [O] . Akio HASHIMOTO 1973

机译：一氧化碳催化氧化过程中铂金氧化碳及氧气的容纳系数

Carbon monoxide assisted self-assembled platinum nanoparticles for catalytic asymmetric hydrogenation

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