Nucleophilicity parameters of enamides and their implications for organocatalytic transformations

Maji B.; Lakhdar S.; Mayr H.

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Nucleophilicity parameters of enamides and their implications for organocatalytic transformations

机译：酰胺的亲核性参数及其对有机催化转化的影响

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The kinetics of the reactions of eleven substituted enamides with benzhydrylium ions (diarylcarbenium ions) were determined in acetonitrile solution. The second-order rate constants follow the correlation log k _2(20°C)=s _N(E+N), which allowed us to derive reactivity parameters N and s _N. With 4.6

机译：在乙腈溶液中测定了11种取代的酰胺与苯甲酰鎓离子（二芳基碳鎓离子）的反应动力学。二阶速率常数遵循相关对数k _2（20°C）= s _N（E + N），这使我们能够得出反应性参数N和s _N。 4.6

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《Chemistry: A European journal》 |2012年第18期|共9页
作者
Maji B.; Lakhdar S.; Mayr H.;
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正文语种 eng
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counterion effect; iminium ions; kinetics; linear free energy relationship; Michael addition;

机译：抗衡离子作用;亚胺离子;动力学;线性自由能关系;迈克尔加成;

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1. Nucleophilicity parameters of enamides and their implications for organocatalytic transformations [J] . Maji B., Lakhdar S., Mayr H. Chemistry: A European journal . 2012,第18期

机译：酰胺的亲核性参数及其对有机催化转化的影响
2. First-Principles Prediction of Nucleophilicity Parameters for π Nucleophiles: Implications for Mechanistic Origin of Mayr’s Equation [J] . Chen Wang, Yao Fu Prof., Qing-Xiang Guo Prof., Chemistry - A European Journal . 2010,第8期

机译：π亲核试剂亲核性参数的第一性原理预测：对Mayr方程机理起源的启示
3. Nucleophilicity Parameters For Phosphoryl-stabilizedcarbanions And Phosphorus Ylides: Implications For Wittigrnand Related Olefination Reactions [J] . Roland Appel, Robert Loos, Herbert Mayr Journal of the American Chemical Society . 2009,第2期

机译：磷酰基稳定的碳负离子和磷叶立德的亲核性参数：对Wittigrn和相关的烯烃化反应的启示
4. Organocatalytic upgrading of biorefining building blocks and subsequent transformation to liquid fuels [C] . Dajiang (DJ) Liu, Eugene Y.-X. Chen National Meeting Exhibition . 2013

机译：生物催化构建块的有机催化升级及随后转化为液体燃料
5. 1. Design and synthesis of phosphino-sulfonamide ligands. 2. Transition metal-catalyzed transformations of enamides and related compounds. [D] . Youm, Ji Youn. 2005

机译：1.设计和合成膦基磺酰胺配体。 2.酰胺和相关化合物的过渡金属催化的转化。
6. Measurement of kinetic parameters for biotransformation of polycyclic aromatic hydrocarbons by trout liver S9 fractions: Implications for bioaccumulation assessment [O] . John W. Nichols, Melanie A. Ladd, Patrick N. Fitzsimmons -1

机译：鳟鱼肝脏S9馏分对多环芳烃进行生物转化的动力学参数的测量：对生物蓄积性评估的意义
7. Catalytic Enantioselective Synthesis of 4-Amino-1,2,3,4-tetrahydropyridine Derivatives from Intramolecular Nucleophilic Addition Reaction of Tertiary Enamides [O] . Shuo Tong, Mei-Xiang Wang 2018

机译：4-氨基-1,2,3,4-四氢吡啶衍生物的催化对映选择性合成来自叔酯的分子内亲核加成反应
8. USE OF TRANSFORMATIONS ON PARAMETERS IN NON-LINEAR THEORY. Ⅱ. MEASURES OF NON-LINEARITY AND TRANSFORMATIONS TO REDUCE NON-LINEARITY [R] . Irwin Guttman, Duane A. Meeter 1964

机译：变换在非线性理论中对参数的应用。 Ⅱ。非线性和变换的措施，以减少非线性

Nucleophilicity parameters of enamides and their implications for organocatalytic transformations

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