A selective palladium-catalyzed carbonylative arylation of aryl ketones to give vinylbenzoate compounds

Schranck J.; Tlili A.; Neumann H.; Alsabeh P.G.; Stradiotto M.; Beller M.

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A selective palladium-catalyzed carbonylative arylation of aryl ketones to give vinylbenzoate compounds

机译：钯催化芳基酮的羰基芳基化反应，生成乙烯基苯甲酸酯化合物

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Preparation of enols: When treated with [{Pd(cinnamyl)Cl} _2]/cataCXium A (nBuPAd_2, Ad=adamantyl) under an atmosphere of CO, aryl ketones react with aryl halides in a carbonylative C-O coupling reaction to form (Z)-vinyl benzoates (see scheme).

机译：烯醇的制备：当在CO气氛下用[{Pd（肉桂基）Cl} _2] / cataCXium A（nBuPAd_2，Ad =金刚烷基）处理时，芳基酮与芳基卤化物在羰基化CO偶联反应中反应形成（Z） -乙烯基苯甲酸酯（参见方案）。

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《Chemistry: A European journal》 |2012年第49期|共6页
作者
Schranck J.; Tlili A.; Neumann H.; Alsabeh P.G.; Stradiotto M.; Beller M.;
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正文语种 eng
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carbonylation; enols; homogeneous catalysis; palladium; vinyl esters;

机译：羰基化;烯醇;均相催化;钯;乙烯基酯;

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1. A selective palladium-catalyzed carbonylative arylation of aryl ketones to give vinylbenzoate compounds [J] . Schranck J., Tlili A., Neumann H., Chemistry: A European journal . 2012,第49期

机译：钯催化芳基酮的羰基芳基化反应，生成乙烯基苯甲酸酯化合物
2. Palladium-Catalyzed Carbonylative Coupling of Aryl Iodides with Alkyl Bromides: Efficient Synthesis of Alkyl Aryl Ketones [J] . Peng Jin-Bao, Chen Bo, Qi Xinxin, Advanced synthesis & catalysis . 2018,第21期

机译：钯催化芳基溴化物的羰基化偶联与烷基溴：烷基芳基酮的有效合成
3. Palladium-Catalyzed Carbonylative Coupling of Aryl Iodides with Alkyl Bromides: Efficient Synthesis of Alkyl Aryl Ketones [J] . Peng Jin-Bao, Chen Bo, Qi Xinxin, Advanced synthesis & catalysis . 2018,第21期

机译：钯催化芳基溴化物的羰基化偶联与烷基溴：烷基芳基酮的有效合成
4. Microwave-Assisted Palladium-Catalyzed Direct Arylation of 1,2,3-Triazoles with Aryl Chlorides [C] . Masayuki Iwasaki, Hideki Yorimitsu, Koichiro Oshima Symposium on Organometallic Chemistry . 2007

机译：微波辅助钯催化的1,2,3-三唑与芳基氯化物的直接芳基
5. Palladium-mediated carbon-carbon bond formation: Methodology and mechanism. Part I: Palladium-catalyzed alpha-arylation of aryl nitromethanes, phosphonoacetates, and phosphine oxides. Part II: Mechanistic study of the palladium-mediated chemoselective activation of C(sp3)-H bonds. [D] . VanGelder, Kelsey Faith. 2016

机译：钯介导的碳-碳键形成：方法和机理。第一部分：芳族硝基甲烷，膦酰基乙酸酯和氧化膦的钯催化α-芳基化反应。第二部分：钯介导的C（sp3）-H键的化学选择性激活的机理研究。
6. Reversed-Polarity Synthesis of Diaryl Ketones through Palladium-Catalyzed Direct Arylation of 2-Aryl-13-dithianes [O] . Baris Yucel, Patrick J. Walsh -1

机译：钯催化2-芳基-13-二硫杂环戊烷的直接芳基化反极性合成二芳基酮
7. Exploration of Aryl Phosphates in Palladium-Catalyzed Mono--arylation of Aryl and Heteroaryl Ketones [O] . -1

机译：钯催化单芳基芳基和杂芳基酮的芳基磷酸盐探测

A selective palladium-catalyzed carbonylative arylation of aryl ketones to give vinylbenzoate compounds

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