F-element-metal bonding and the use of the bond polarity to build molecular intermetalloids

Oelkers B.; Butovskii M.V.; Kempe R.

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F-element-metal bonding and the use of the bond polarity to build molecular intermetalloids

机译：F-元素-金属键合和利用键合极性构建分子间金属

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Metal-metal bonding in heterobimetallic complexes is of fundamental interest due to its implications to both bonding theory and new reactivities. In this Concept, structurally authenticated molecular compounds with direct bonds between rare-earth metals or actinoids and transition or main group metals are summarized. Special attention is given to the use of bond polarity as a tool for designing molecular intermetalloids incorporating rare-earth atoms and transition metals.

机译：异双金属配合物中的金属-金属键合具有根本的意义，因为它对键合理论和新的反应性都有影响。在本概念中，概述了在稀土金属或act系元素与过渡金属或主族金属之间具有直接键的结构经过验证的分子化合物。特别注意将键极性用作设计结合稀土原子和过渡金属的分子间金属的工具。

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《Chemistry: A European journal》 |2012年第43期|共14页
作者
Oelkers B.; Butovskii M.V.; Kempe R.;
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正文语种 eng
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关键词
actinides; bond theory; intermetalloids; lanthanides; metal-metal interactions;

机译：in系元素;键理论;金属间化合物;镧系元素;金属-金属相互作用;

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机译：F-元素-金属键合和利用键合极性构建分子间金属
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F-element-metal bonding and the use of the bond polarity to build molecular intermetalloids

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