Self-assembled Pd _6 open cage with triimidazole walls and the use of its confined nanospace for catalytic knoevenagel- and diels-alder reactions in aqueous medium

Samanta D.; Mukherjee S.; Patil Y.P.; Mukherjee P.S.

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Self-assembled Pd _6 open cage with triimidazole walls and the use of its confined nanospace for catalytic knoevenagel- and diels-alder reactions in aqueous medium

机译：具有三咪唑壁的自组装Pd _6开笼及其在水介质中的纳米空间催化Knoevenagel和Diels-Alder反应的应用

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The two-component self-assembly of a 90° Pd ~(II) acceptor and a triimidazole donor led to the formation of a water-soluble semi-cylindrical cage with a hydrophobic cavity, which was separately crystallized with hydrophilic- and hydrophobic guests. The parent cage was found to catalyze the Knoevenagel condensation reaction of a series of aromatic mono-aldehydes with active methylene compounds, such as Meldrum's acid or 1,3-dimethylbarbituric acid. The confined hydrophobic nanospace within this cage was also used in the catalytic Diels-Alder reactions of 9-hydroxymethylanthracene with N-phenylmaleimide or N-cyclohexylmaleimide.

机译：90°Pd〜（II）受体和三咪唑供体的两组分自组装导致形成具有疏水腔的水溶性半圆柱笼，该笼分别用亲水和疏水客体结晶。发现母笼催化了一系列芳族单醛与活性亚甲基化合物（如麦德鲁姆酸或1,3-二甲基巴比妥酸）的Knoevenagel缩合反应。该笼中的疏水性纳米空间也被用于9-羟甲基蒽与N-苯基马来酰亚胺或N-环己基马来酰亚胺的Diels-Alder催化反应中。

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《Chemistry: A European journal》 |2012年第39期|共8页
作者
Samanta D.; Mukherjee S.; Patil Y.P.; Mukherjee P.S.;
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正文语种 eng
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cage compounds; host-guest systems; imidazole; palladium; self-assembly;

机译：笼状化合物;主客体系统;咪唑;钯;自组装;

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1. Self-assembled Pd _6 open cage with triimidazole walls and the use of its confined nanospace for catalytic knoevenagel- and diels-alder reactions in aqueous medium [J] . Samanta D., Mukherjee S., Patil Y.P., Chemistry: A European journal . 2012,第39期

机译：具有三咪唑壁的自组装Pd _6开笼及其在水介质中的纳米空间催化Knoevenagel和Diels-Alder反应的应用
2. Nanospace-Confined High-Temperature Solid-State Reactions: Versatile Synthetic Route for High-Diversity Pool of Catalytic Nanocrystals [J] . Jung Hun Koo, Si Woo Lee, Jeong Young Park, Chemistry of Materials: A Publication of the American Chemistry Society . 2017,第21期

机译：纳米空间限制高温固态反应：高多样性催化纳米晶体池的多功能合成路线
3. Diels-Alder Reactions of Inert Aromatic Compounds within a Self-Assembled Coordination Cage [J] . Shinnosuke Horiuchi, Takashi Murase, Makoto Fujita Chemistry, an Asian journal . 2011,第7期

机译：自组装配位笼内惰性芳香化合物的Diels-Alder反应
4. Diels-Alder Reaction of Anthracenes in Aqueous Self-Assembled Hosts: Unusual Regioselectivity and Efficient Catalysis [C] . Michito Yoshizawa, Masazumi Tamura, Makoto Fujita Symposium on Organometallic Chemistry . 2006

机译：蒽酮在水性自组装寄主水中的酰亚胺反应：不寻常的区域选择性和有效的催化
5. Development of three reaction methodologies en route to nitrogen containing heterocycles: A Diels-Alder/Schmidt, a Diels-Alder/acylation and a catalytic intramolecular Schmidt. [D] . Hirt, Erin E. 2009

机译：三种反应方法在含氮杂环反应中的发展：Diels-Alder / Schmidt，Diels-Alder /酰化反应和催化分子内Schmidt。
6. Cage-bell Pt-Pd nanostructures with enhanced catalytic properties and superior methanol tolerance for oxygen reduction reaction [O] . Dong Chen, Feng Ye, Hui Liu, -1

机译：笼式钟形Pt-Pd纳米结构具有增强的催化性能和出色的甲醇耐受性可进行氧还原反应
7. A Self-Assembled Molecular Cage for Substrate-Selective Epoxidation Reactions in Aqueous Media [O] . Petrus F. Kuijpers, Matthias Otte, Maximilian Dürr, 2016

机译：用于含水介质中的底物选择性环氧化反应的自组装分子笼

Self-assembled Pd _6 open cage with triimidazole walls and the use of its confined nanospace for catalytic knoevenagel- and diels-alder reactions in aqueous medium

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