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首页> 外文期刊>Chemistry: A European journal >Design, synthesis, and miniemulsion polymerization of new phosphonate surfmers and application studies of the resulting nanoparticles as model systems for biomimetic mineralization and cellular uptake
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Design, synthesis, and miniemulsion polymerization of new phosphonate surfmers and application studies of the resulting nanoparticles as model systems for biomimetic mineralization and cellular uptake

机译：新型膦酸酯表面活性剂的设计，合成和细乳液聚合，以及所得纳米颗粒作为仿生矿化和细胞吸收模型系统的应用研究

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摘要

Heterophase polymerizations have gained increasing attention in the past decades, especially as the decoration and functionalization of the particle surface for further applications gets more and more into focus. One promising approach for the functionalization exclusively on the particle surface is the use of surfmers (surfactant and monomer). Herein, we present the synthesis of a new family of surfmers and their use for decorating nanoparticles with phosphonate groups through miniemulsion polymerization. Furthermore the synthesis of a dye-labeled functional surfmer provided an elegant manner to evaluate and get deeper insights about its copolymerization. Additionally, potential applications of the synthesized particles in biological studies as well as their use as template for biomimetic mineralization are presented.
机译：在过去的几十年中，尤其是随着用于进一步应用的颗粒表面的装饰和功能化越来越受到关注，异相聚合越来越受到关注。仅在颗粒表面上进行功能化的一种有前途的方法是使用表面活性剂（表面活性剂和单体）。在本文中，我们介绍了新的冲浪剂家族的合成及其在微乳液聚合中修饰具有膦酸酯基团的纳米颗粒的用途。此外，染料标记的功能性冲浪剂的合成提供了一种优雅的方式来评估其共聚作用并获得更深入的见解。此外，还介绍了合成颗粒在生物学研究中的潜在应用以及它们作为仿生矿化模板的用途。

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