The first catalytic synthesis of an acrylate from CO _2 and an alkene-A rational approach

Lejkowski M.L.; Lindner R.; Kageyama T.; Bódizs G.E.; Plessow P.N.; Müller I.B.; Sch?fer A.; Rominger F.; Hofmann P.; Futter C.; Schunk S.A.; Limbach M.

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The first catalytic synthesis of an acrylate from CO _2 and an alkene-A rational approach

机译：CO _2和烯烃的丙烯酸催化首次合成-A合理方法

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For more than three decades the catalytic synthesis of acrylates from the cheap and abundantly available C _1 building block carbon dioxide and alkenes has been an unsolved problem in catalysis research, both in academia and industry. Herein, we describe a homogeneous catalyst based on nickel that permits the catalytic synthesis of the industrially highly relevant acrylate sodium acrylate from CO _2, ethylene, and a base, as demonstrated, at this stage, by a turnover number of greater than 10 with respect to the metal.

机译：在过去的三十多年中，无论是在学术界还是工业界，由廉价且大量可用的C _1结构单元二氧化碳和烯烃催化合成丙烯酸酯一直是催化研究中尚未解决的问题。本文中，我们描述了一种基于镍的均相催化剂，该催化剂允许从CO _2，乙烯和碱催化合成工业上高度相关的丙烯酸钠丙烯酸酯钠，如该阶段所示，相对于10金属。

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《Chemistry: A European journal》 |2012年第44期|共9页
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Lejkowski M.L.; Lindner R.; Kageyama T.; Bódizs G.E.; Plessow P.N.; Müller I.B.; Sch?fer A.; Rominger F.; Hofmann P.; Futter C.; Schunk S.A.; Limbach M.;
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正文语种 eng
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C 1 building blocks; carbon dioxide fixation; carboxylation; homogeneous catalysis; nickel;

机译：C 1结构单元;二氧化碳固定;羧化;均相催化;镍;

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1. The first catalytic synthesis of an acrylate from CO _2 and an alkene-A rational approach [J] . Lejkowski M.L., Lindner R., Kageyama T., Chemistry: A European journal . 2012,第44期

机译：CO _2和烯烃的丙烯酸催化首次合成-A合理方法
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机译：新型多相催化剂的系统合成，表征及催化活性的综合方法。最终进展报告

The first catalytic synthesis of an acrylate from CO _2 and an alkene-A rational approach

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