Temperature-dependent capture of water molecules by saddle-shaped hexanuclear carboxylate cycloclusters in a (3,18)-connected metal-organic framework

Han Y.; Xu H.; Liu Y.; Li H.; Hou H.; Fan Y.; Batten S.R.

首页> 外文期刊>Chemistry: A European journal >Temperature-dependent capture of water molecules by saddle-shaped hexanuclear carboxylate cycloclusters in a (3,18)-connected metal-organic framework

【24h】

Temperature-dependent capture of water molecules by saddle-shaped hexanuclear carboxylate cycloclusters in a (3,18)-connected metal-organic framework

机译：（3,18）-连接的金属-有机骨架中的鞍形六核羧酸盐环簇对水分子的温度依赖性捕获

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A new (3,18)-connected 3D metal-organic framework [Co(PYNT)(H _2O) _2] _n (ZZU-1) (H _2PYNT=5-(3'- carboxylphenyl) nicotic acid) has been reported. Amazingly, ZZU-1 captures water molecules and transforms into the hydrated framework {[Co _3(PYNT) _3(H _2O) _6]·H _2O} _n (ZZU-2) at 160 °C in refluxing hydrated DMF, but not at 100 °C in refluxing neat water or from the solvothermal synthesis conducted at 90 °C (see figure).

机译：已经报道了新的（3,18）连接的3D金属有机框架[Co（PYNT）（H _2O）_2] _n（ZZU-1）（H _2PYNT = 5-（3'-羧基苯基）烟酸）。令人惊奇的是，ZZU-1在回流的水合DMF中于160°C捕获水分子并转化为水合骨架{[Co _3（PYNT）_3（H _2O）_6]·H _2O} _n（ZZU-2），但在在100°C的回流纯水中或在90°C下进行的溶剂热合成（见图）。

著录项

来源
《Chemistry: A European journal》 |2012年第44期|共5页
作者
Han Y.; Xu H.; Liu Y.; Li H.; Hou H.; Fan Y.; Batten S.R.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词
capture; magnetic properties; metal-organic frameworks; UV/Vis spectroscopy; water clusters;

机译：捕获;磁性;金属有机框架;紫外/可见光谱;水团簇;

相似文献

外文文献
中文文献
专利

1. Temperature-dependent capture of water molecules by saddle-shaped hexanuclear carboxylate cycloclusters in a (3,18)-connected metal-organic framework [J] . Han Y., Xu H., Liu Y., Chemistry: A European journal . 2012,第44期

机译：（3,18）-连接的金属-有机骨架中的鞍形六核羧酸盐环簇对水分子的温度依赖性捕获
2. A robust and water-stable two-fold interpenetrated metal-organic framework containing both rigid tetrapodal carboxylate and rigid bifunctional nitrogen linkers exhibiting selective CO2 capture [J] . Gupta Vijay, Mandal Sanjay K. Dalton transactions: An international journal of inorganic chemistry . 2019,第2期

机译：稳健和水稳定的双折叠金属 - 有机骨架，其含有刚性四腔羧酸盐和刚性双官能氮连物，其具有选择性CO2捕获
3. Enhancing Proton Conductivity in a 3D Metal-Organic Framework by the Cooperation of Guest [Me2NH2](+) Cations, Water Molecules, and Host Carboxylates [J] . Zou Lifei, Yao Shuo, Zhao Jun, Crystal growth & design . 2017,第6期

机译：通过访客[ME2NH2]（+）阳离子，水分子和宿主羧酸盐的合作，提高3D金属有机框架中的质子电导率
4. Optical and emission properties of dye molecules captured in the mesoscale channels of micron-sized metal-organic framework crystals [C] . Seong Huh, In-Hwan Choi, Youngmee Kim Microoptics Conference . 2017

机译：在微米级金属-有机骨架晶体的中尺度通道中捕获的染料分子的光学和发射特性
5. Synthesis and Structural Characterization of Carboxylate-Based Metal-Organic Frameworks and Coordination Networks. [D] . Calderone, Paul. 2012

机译：羧酸盐基金属有机骨架和配位网络的合成和结构表征。
6. Photophysical properties of cationic dyes captured in the mesoscale channels of micron-sized metal-organic framework crystals [O] . In-Hwan Choi, Suk Bin Yoon, Seong Huh, -1

机译：在微米级金属-有机骨架晶体的中尺度通道中捕获的阳离子染料的光物理性质
7. Encapsulation of Water Cluster, meso-Helical Chain and Tapes in Metal-Organic Frameworks Based on Double-Stranded Cd(II) Helicates and Carboxylates [O] . -1

机译：基于双链CD（II）螺旋和羧酸盐的金属 - 有机框架中的水簇，中间螺旋链和带胶带的封装

Temperature-dependent capture of water molecules by saddle-shaped hexanuclear carboxylate cycloclusters in a (3,18)-connected metal-organic framework

摘要

著录项

相似文献

相关主题

期刊订阅