Modulation of homochiral Dy~III complexes: Single-molecule magnets with ferroelectric properties

Li X.-L.; Chen C.-L.; Gao Y.-L.; Liu C.-M.; Feng X.-L.; Gui Y.-H.; Fang S.-M.

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Modulation of homochiral Dy~III complexes: Single-molecule magnets with ferroelectric properties

机译：同手性Dy〜III配合物的调制：具有铁电特性的单分子磁体

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Homochiral Dy~III complexes: By changing the ligand-to-metal ratio, enantiomeric pairs of a Dy~III complex of different nuclearity could be obtained. The mono- and dinuclear complexes exhibit characteristics of single-molecule magnets and different slow magnetic relaxation processes. In addition, the dinuclear complexes (see picture) exhibit ferroelectric behavior, thus representing the first chiral polynuclear lanthanide-based single-molecule magnets with ferroelectric properties.

机译：同手性Dy〜III配合物：通过改变配体与金属的比例，可以获得具有不同核度的Dy〜III配合物的对映体对。单核和双核复合物表现出单分子磁体的特征和不同的慢磁弛豫过程。此外，双核配合物（参见图片）具有铁电行为，因此代表了首个具有铁电特性的手性多核镧系元素单分子磁体。

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《Chemistry: A European journal》 |2012年第46期|共6页
作者
Li X.-L.; Chen C.-L.; Gao Y.-L.; Liu C.-M.; Feng X.-L.; Gui Y.-H.; Fang S.-M.;
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正文语种 eng
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关键词
chirality; dysprosium; ferroelectricity; magnetic properties; single-molecule magnets;

机译：手性;dy;铁电性;磁性;单分子磁体;

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1. Modulation of homochiral Dy~III complexes: Single-molecule magnets with ferroelectric properties [J] . Li X.-L., Chen C.-L., Gao Y.-L., Chemistry: A European journal . 2012,第46期

机译：同手性Dy〜III配合物的调制：具有铁电特性的单分子磁体
2. A zigzag Dy_4~(III) cluster exhibiting single-molecule magnet, ferroelectric and white-light emitting properties [J] . Peng-Hu Guo, Yan Meng, Yan-Cong Chen Journal of Materials Chemistry, C. materials for optical and electronic devices . 2014,第42期

机译：具有单分子磁体，铁电和白光发射特性的锯齿形Dy_4〜（III）团簇
3. Single-Molecule Magnet Behavior and Magnetocaloric Effect in Ferromagnetically Coupled Ln~(III)-Ni~(II)-Ni~(II)-Ln~(III) (Ln~(III) = Dy~(III) and Gd~(III)) Linear Complexes [J] . Carlos Meseguer, Silvia Titos-Padilla, Mikko M. Ha?nninen, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2014,第22期

机译：铁磁耦合的Ln〜（III）-Ni〜（II）-Ni〜（II）-Ln〜（III）中的单分子磁体行为和磁热效应（Ln〜（III）= Dy〜（III）和Gd〜（ III））线性络合物
4. The local magnetic properties of Mn_6~(III) Cr~(III)~(3+) and Fe_6~(III) Cr~(III)~(3+) single-molecule magnets deposited on surfaces studied by spin-polarized photoemission and XMCD with circularly polarized synchrotron radiation [C] . U. Heinzmann, A. Helmstedt, N. Dohmeier, ICPEAC . 2014

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5. Investigating the modulation of monometallic single-molecule magnets through peripheral ligand modifications [D] . Ghorbanian Farahabadi, Nastaran 2013

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6. Redox-Modulations of Photophysical and Single-molecule Magnet Properties in Ytterbium Complexes Involving Extended-TTF Triads [O] . Bertrand Lefeuvre, Jessica Flores Gonzalez, Frédéric Gendron, 2020

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7. Single-molecule magnet behavior in luminescent carbazolyl Dy(iii) octahedral complexes with a quasi linear N−–Dy–N− angle [O] . Jérôme Long, Alexander N. Selikhov, Ekaterina Mamontova, 2020

机译：发光咔唑基DY（III）八面体络合物中的单分子磁体行为，用拟线性N - Dy-n - 角度

Modulation of homochiral Dy~III complexes: Single-molecule magnets with ferroelectric properties

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