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Multielectron-transfer templates via consecutive two-electron transformations: Iron-sulfur complexes relevant to biological enzymes

机译:通过连续的两个电子转换的多电子转移模板:与生物酶有关的铁硫配合物

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摘要

[FeFe] hydrogenase mimics: Two polynuclear iron-sulfur complexes (1 and 2; see figure) were prepared and structurally characterized. They are potentially effective and stable multielectron-transfer relays for mediating four- and six-electron transformations via a cascade of reversible two-electron redox steps with relatively narrow potential spans.
机译:[FeFe]氢化酶模拟物:制备了两种多核铁硫配合物(1和2;见图)。它们是潜在的有效且稳定的多电子传输继电器,用于通过级联可逆的两电子氧化还原步骤(电位跨度相对较窄)来介导四电子和六电子转换。

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