首页> 外文期刊>Chemistry: A European journal >Tetrakis(phthalocyaninato) rare-earth-cadmium-rare-earth quadruple-decker sandwich SMMs: Suppression of QTM by long-distance f-f interactions
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Tetrakis(phthalocyaninato) rare-earth-cadmium-rare-earth quadruple-decker sandwich SMMs: Suppression of QTM by long-distance f-f interactions

机译:Tetrakis(phthalocyaninato)稀土-镉-稀土-稀土四层夹层SMMs:通过远距离f-f相互作用抑制QTM

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摘要

Long-distance f-f interactions: Systematic and comparative studies of the magnetic properties of a series of isostructural sandwich-type tetrakis-ACHTUNGTRENUNG(phthalocyaninato) diterbium and monoterbium quadruple-decker complexes clearly reveal the suppression of the quantum tunneling of magnetization by the long-distance intramolecular f-f interactions (see figure).
机译:远距离ff相互作用:系统和比较研究一系列同构夹心结构的四价--ACH钨酸T(phthal酞菁)二ter和一ter四重dec层配合物,清楚地揭示了长距离对磁化量子隧穿的抑制分子内ff相互作用(见图)。

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