A cooperative hydrogen-bond-promoted organophotoredox catalysis strategy for highly diastereoselective, reductive enone cyclization

Neumann M.; Zeitler K.

首页> 外文期刊>Chemistry: A European journal >A cooperative hydrogen-bond-promoted organophotoredox catalysis strategy for highly diastereoselective, reductive enone cyclization

【24h】

A cooperative hydrogen-bond-promoted organophotoredox catalysis strategy for highly diastereoselective, reductive enone cyclization

机译：协同氢键促进的有机光氧化还原催化策略，用于高度非对映选择性，还原性烯酮环化

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Metal-free cooperation: The cooperative combination of EosinY as a photoredox catalyst with organocatalytic thiourea allows for the highly diastereoselective construction of trans-1,2-cycloalkanes and heterocycles. This new efficient, cooperative organophotoredox/organocatalysis protocol presents a valuable alternative to metal-based photoredox approaches and is the first example of combining photoredox with hydrogen-bond catalysis (see scheme).

机译：无金属配合：曙红Y作为一种光氧化还原催化剂与有机催化硫脲的配合组合可实现反式1，2-环烷烃和杂环的高度非对映选择性。这种新的高效，协作的有机光氧化还原/有机催化方案为基于金属的光氧化还原方法提供了一种有价值的替代方法，并且是将光氧化还原与氢键催化结合的第一个示例（参见方案）。

著录项

来源
《Chemistry: A European journal》 |2013年第22期|共6页
作者
Neumann M.; Zeitler K.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词
organocatalysis; photocatalysis; redox chemistry; reductive cyclization; thiourea;

机译：有机催化;光催化;氧化还原化学;还原环化;硫脲;

相似文献

外文文献
中文文献
专利

1. A cooperative hydrogen-bond-promoted organophotoredox catalysis strategy for highly diastereoselective, reductive enone cyclization [J] . Neumann M., Zeitler K. Chemistry: A European journal . 2013,第22期

机译：协同氢键促进的有机光氧化还原催化策略，用于高度非对映选择性，还原性烯酮环化
2. Highly Diastereoselective Cationic Cyclization Reactions Convert a Common Monocyclic Enone to Bicyclic Precursors for the Synthesis of Retigeranic Acids A and B [J] . Breitler Simon, Han Yixin, Corey E. J. Organic letters . 2017,第24期

机译：高度非致对阳离子环化反应转化为双环前体转化常见的单环烯酮，用于合成果酸酸A和B.
3. Highly efficient extractive biocatalysis in the asymmetric reduction of an acyclic enone by the yeast Pichia stipitis [J] . Conceicao GJA., Moran PJS., Rodrigues JAR. Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2003,第1期

机译：酵母毕赤酵母不对称还原无环烯酮的高效提取生物催化
4. Highly Diastereoselective Tandem Reduction-Allylation Reactions of 1,4-Diketones with Zirconocene-Olefin Complexes [C] . Kazuya Fujita, Hiroshi Shinokubo, Koichiro Oshima Symposium on Organometallic Chemistry . 2003

机译：用锆茂 - 烯烃配合物的1,4-二酮的高度映射串联酸化 - 烯丙基化反应
5. Development of highly diastereoselective FeCl3 catalyzed prins and Friedel-Crafts cyclization and investigation of highly substituted tetrahydropyrans via Cu(OTf)2-bisphosphine olefin migration-prins cyclization. [D] . Keyes, Chad A. 2014

机译：高度非对映选择性的FeCl3催化蛋白的开发和Friedel-Crafts环化，以及通过Cu（OTf）2-双膦烯烃迁移-蛋白环化对高度取代的四氢吡喃的研究。
6. Highly Diastereoselective Synthesis of Tetrahydropyridines by a C–H Activation–Cyclization–Reduction Cascade [O] . Simon Duttwyler, Colin Lu, Arnold L. Rheingold, -1

机译：四氢吡啶的高度选择性合成由C-H活化的环化 - 还原级联
7. Highly diastereoselective synthesis of cyclopentenones via a one-pot gold catalysis, Nazarov cyclization and alkylation cascade [O] . Liu Meng-Qi, Zhou Ai-Hua, Jiang Shuang, 2014

机译：通过一锅金催化，纳扎罗夫环化和烷基化级联反应高度非对映选择性合成环戊烯酮

A cooperative hydrogen-bond-promoted organophotoredox catalysis strategy for highly diastereoselective, reductive enone cyclization

摘要

著录项

相似文献

相关主题

期刊订阅