Cobalt(II)-catalyzed 1,4-addition of organoboronic acids to activated alkenes: An application to highly cis-stereoselective synthesis of aminoindane carboxylic acid derivatives

Chen M.-H.; Mannathan S.; Lin P.-S.; Cheng C.-H.

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Cobalt(II)-catalyzed 1,4-addition of organoboronic acids to activated alkenes: An application to highly cis-stereoselective synthesis of aminoindane carboxylic acid derivatives

机译：钴（II）催化的有机硼酸向活化烯烃的1,4-加成：对氨基茚满羧酸衍生物的高度顺式立体选择性合成的应用

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It all adds up: The 1,4-addition of organoboronic acids to activated alkenes catalyzed by [Co(dppe)Cl_2] is described. A [3+2]-annulation reaction of ortho-iminoarylboronic acids with acrylates to give various aminoindane carboxylic acid derivatives with cis-stereoselectivity is also demonstrated (see scheme; dppe=1,2-bis(diphenylphosphino)ethane).

机译：全部加起来：描述了由[Co（dppe）Cl_2]催化的有机硼酸向活化烯烃的1,4-加成。还证明了邻亚氨基亚芳基硼酸与丙烯酸酯的[3 + 2]环化反应，得到具有顺式-立体选择性的各种氨基茚满羧酸衍生物（见方案; dppe = 1,2-双（二苯基膦基）乙烷）。

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《Chemistry: A European journal》 |2012年第47期|共5页
作者
Chen M.-H.; Mannathan S.; Lin P.-S.; Cheng C.-H.;
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1; 4-addition; alkenes; aminoindanes; annulation; boron; cobalt;

机译：1;4-加成;烯烃;氨基茚满;环化;硼;钴;

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1. Cobalt(II)-catalyzed 1,4-addition of organoboronic acids to activated alkenes: An application to highly cis-stereoselective synthesis of aminoindane carboxylic acid derivatives [J] . Chen M.-H., Mannathan S., Lin P.-S., Chemistry: A European journal . 2012,第47期

机译：钴（II）催化的有机硼酸向活化烯烃的1,4-加成：对氨基茚满羧酸衍生物的高度顺式立体选择性合成的应用
2. Cobalt-catalyzed addition reaction of organoboronic acids with aldehydes: Highly enantioselective synthesis of diarylmethanols [J] . Karthikeyan J., Jeganmohan M., Cheng C.-H. Chemistry: A European journal . 2010,第30期

机译：钴催化的有机硼酸与醛的加成反应：二芳基甲醇的高度对映选择性合成
3. Cobalt-Catalyzed Addition Reaction of Organoboronic Acids with Aldehydes: Highly Enantioselective Synthesis of Diarylmethanols [J] . Jaganathan Karthikeyan Masilamani Jeganmohan Dr. Chien-Hong Cheng Prof. Dr. Chemistry - A European Journal . 2010,第30期

机译：钴催化的有机硼酸与醛的加成反应：二芳基甲醇的高对映选择性合成
4. Catalytic Asymmetric Construction of Quaternary Stereocenters through Rhodium-Catalyzed Addition of Organoboronic Acids [C] . Ryo Shintani, Wei-Liang Duan, Mitsunori Inoue Symposium on Organometallic Chemistry . 2006

机译：通过铑催化加入有机硼酸催化不对称结构的季型立体封闭
5. Exploration of alpha-Diazocarbonyl Compounds for Transition-Metal Catalyzed Carbon-Carbon Bond Formations. Development of Palladium-Catalyzed Stereoselective Synthesis of Trisubstituted Alkenes and the Synthesis of Quaternary alpha,alpha-Heterodiaryl Carboxylic Acids by Rhodium-Catalyzed Multi-Component Coupling Reactions. [D] . Tsoi, Yuk Tai. 2012

机译：探索用于过渡金属催化的碳-碳键形成的α-重氮羰基化合物。铑催化的多组分偶合反应在钯催化的立体选择性合成三取代的烯烃上的发展和季铵的α，α-杂二芳基羧酸的合成。
6. Asymmetric Pd-Catalyzed Alkene Carboamination Reactions for the Synthesis of 2-Aminoindane Derivatives [O] . Derick R. White, Johnathon T. Hutt, John P. Wolfe -1

机译：不对称钯催化的烯烃碳氨基化反应合成2-氨基茚满衍生物
7. Rhodium-Catalyzed Asymmetric 1,4-Addition of Organoboronic Acids and Their Derivatives to Electron Deficient Olefins [O] . Tamio Hayashi 2001

机译：铑催化的不对称1,4-加入有机硼酸及其衍生物以电子缺乏烯烃

Cobalt(II)-catalyzed 1,4-addition of organoboronic acids to activated alkenes: An application to highly cis-stereoselective synthesis of aminoindane carboxylic acid derivatives

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