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首页> 外文期刊>Chemistry: A European journal >Supramolecular Assembly with Multiple Preorganised p-Electronic Cages
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Supramolecular Assembly with Multiple Preorganised p-Electronic Cages

机译：具有多个预组织p电子笼的超分子组装

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The construction of highly ordered assemblies with welldefined topology is an important topic in the fields of chemistry, materials, and life sciences, as they always uncover fascinating and unexpected functionality that cannot be obtained with simple building blocks.~([1]) A variety of noncovalent interactions have been employed as driving forces for the formation of highly ordered assemblies including hydrogen-bonding,~([2]) metal-ligand coordination,~([3]) p···p stacking~([4]) and host-guest couples.~([5]) To build truly operational supramolecular materials, extremely strong interactions between subunits is a prerequisite to achieve positive cooperative effects. As a consequence, multivalent binding has emerged as an effective strategy that introduces multiple simple binding modes into one rationally designed monomer.~([6]) This straightforward strategy has been ubiquitously practiced in diverse biorecognition processes,~([7]) such as RNA metabolism, peptide folding, cellular signaling and carbohydrate- protein interactions. Inspired by nature, artificial assemblies~([8]) have gained considerable attention in recent years, in whichmultivalent binding plays a key role in building highly ordered nanoarchitectures with well-defined topology, optimising and amplifying their desired physicochemical properties.
机译：具有良好拓扑结构的高度有序的装配体的构造是化学，材料和生命科学领域的重要主题，因为它们始终会发现用简单的构造块无法获得的引人入胜的意外功能。〜[[1]）非共价相互作用被用作形成包括氢键，〜（[2]）金属-配体配位，〜（[3]）p··p堆积〜（[4]）的高度有序组装体的驱动力〜（[5]）要构建真正可操作的超分子材料，亚基之间极强的相互作用是取得积极合作效应的前提。结果，多价结合已成为一种有效的策略，将多种简单的结合模式引入一个合理设计的单体中。〜（[6]）这种直接的策略已广泛应用于各种生物识别过程中，例如（[7]），例如RNA代谢，肽折叠，细胞信号传导和糖蛋白相互作用。受自然界的启发，人工组装[8]近年来受到了相当大的关注，其中多价结合在构建具有明确拓扑的高度有序的纳米结构，优化和放大其所需的理化特性方面起着关键作用。

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