Carbodeoxygenation of biomass: The carbonylation of glycerol and higher polyols to monocarboxylic acids

Coskun T.; Conifer C.M.; Stevenson L.C.; Britovsek G.J.P.

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Carbodeoxygenation of biomass: The carbonylation of glycerol and higher polyols to monocarboxylic acids

机译：生物质的碳脱氧：甘油和高级多元醇羰基化为一元羧酸

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Glycerol is converted to a mixture of butyric and isobutyric acid by rhodium- or iridium-catalysed carbonylation using HI as the co-catalyst. The initial reaction of glycerol with HI results in several intermediates that lead to isopropyl iodide, which upon carbonylation forms butyric and isobutyric acid. At low HI concentration, the intermediate allyl iodide undergoes carbonylation to give vinyl acetic acid and crotonic acid. Higher polyols C_nH _(n+2)(OH)_n are carbonylated to the corresponding C _(n+1) mono-carboxylic acids.

机译：使用HI作为助催化剂，通过铑或铱催化的羰基化作用将甘油转化为丁酸和异丁酸的混合物。甘油与HI的初始反应产生了几种中间体，这些中间体可生成异丙基碘化物，在羰基化反应后会形成丁酸和异丁酸。在低HI浓度下，中间体烯丙基碘经过羰基化反应生成乙烯基乙酸和巴豆酸。高级多元醇C_nH_（n + 2）（OH）_n被羰基化为相应的C_（n + 1）一元羧酸。

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《Chemistry: A European journal》 |2013年第21期|共5页
作者
Coskun T.; Conifer C.M.; Stevenson L.C.; Britovsek G.J.P.;
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正文语种 eng
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butyric acid; carbon monoxide; carbonylation; glycerol; iridium; rhodium;

机译：丁酸;一氧化碳;羰基化;甘油;铱;铑;

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1. Carbodeoxygenation of biomass: The carbonylation of glycerol and higher polyols to monocarboxylic acids [J] . Coskun T., Conifer C.M., Stevenson L.C., Chemistry: A European journal . 2013,第21期

机译：生物质的碳脱氧：甘油和高级多元醇羰基化为一元羧酸
2. Chemicals from biomass: Synthesis of glycerol carbonate by transesterification and carbonylation with urea with hydrotalcite catalysts. The role of acid-base pairs [J] . Climent M.J., Corma A., De Frutos P., Journal of Catalysis . 2010,第1期

机译：生物质中的化学物质：通过酯交换反应和水滑石催化剂与尿素羰基化合成碳酸甘油酯。酸碱对的作用
3. An efficient didehydroxylation method for the biomass-derived polyols glycerol and erythritol. Mechanistic studies of a formic acid-mediated deoxygenationt [J] . Elena Arceo, Peter Marsden, Robert G. Bergman, Chemical Communications . 2009,第23期

机译：用于生物质衍生的多元醇甘油和赤藓糖醇的有效二去羟基化方法。甲酸介导的脱氧的机理研究
4. SYNTHESIS OF GLYCEROL CARBONATE BY CARBONYLATION OF GLYCEROL AND UREA USING METAL ORGANIC FRAMEWORK AS CATALYSTS [C] . M.J. KIM, D.W. KIM, D.H. KANG, IUPAC 10th International conference on novel materials and their synthesis: Book of abstracts . 2014

机译：金属有机框架催化甘油与尿素的羰基化合成碳酸甘油酯。
5. Inhibitory Effects of Acids Found in Crude Glycerol and Lignocellulosic Biomass on Clostridium pasteurianum for Butanol Production [D] . Duncan, Caroline E. 2020

机译：在丁醇生产中粗甘油和木质纤维素生物量发现酸中酸的抑制作用
6. Long-Chain Glycerol Diether and Polyol Dialkyl Glycerol Triether Lipids of Sulfolobus acidocaldarius [O] . Thomas A. Langworthy, William R. Mayberry, Paul F. Smith 1974

机译：嗜酸硫杆菌的长链甘油二醚和多元醇二烷基甘油三醚脂质
7. Carbodeoxygenation of Biomass: The Carbonylation of Glycerol and Higher Polyols to Monocarboxylic Acids [O] . Coskun T, Conifer CM, Stevenson LC, 2013

机译：生物质的碳氧合作用：甘油和高级多元醇羰基化为单羧酸

Carbodeoxygenation of biomass: The carbonylation of glycerol and higher polyols to monocarboxylic acids

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