TIPS-TTF as a precursor of low-symmetry TTF derivatives: Steric protection strategy in the regioselective C-H modification of TTF

Ueno R.; Fujino D.; Yorimitsu H.; Osuka A.

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TIPS-TTF as a precursor of low-symmetry TTF derivatives: Steric protection strategy in the regioselective C-H modification of TTF

机译：TIPS-TTF作为低对称TTF衍生物的前体：TTF区域选择性C-H修饰中的立体保护策略

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Triisopropylsilyltetrathiafulvalene (TIPS-TTF) has been devised as a promising platform for the synthesis of low-symmetry TTF derivatives. The bulky TIPS group allows TIPS-TTF to undergo palladium-catalyzed direct diarylation as well as LDA-mediated dilithiation exclusively on the roomier dithiole ring. Subsequent fluoride-mediated protodesilylation provided vicinally difunctionalized TTF, which could undergo further functionalization. (LDA=lith

机译：三异丙基甲硅烷基四硫富瓦烯（TIPS-TTF）已被设计为合成低对称TTF衍生物的有前途的平台。庞大的TIPS基团允许TIPS-TTF仅在更宽敞的二硫醇环上进行钯催化的直接二芳基化以及LDA介导的二氢化。随后的氟化物介导的protodesilylation提供了病毒双官能化的TTF，可以进一步进行功能化。（LDA =石

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《Chemistry: A European journal》 |2013年第22期|共6页
作者
Ueno R.; Fujino D.; Yorimitsu H.; Osuka A.;
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正文语种 eng
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C-H modification; heterocycles; palladium; regioselectivity; steric hindrance;

机译：碳氢修饰;杂环;钯;区域选择性;位阻;

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1. TIPS-TTF as a precursor of low-symmetry TTF derivatives: Steric protection strategy in the regioselective C-H modification of TTF [J] . Ueno R., Fujino D., Yorimitsu H., Chemistry: A European journal . 2013,第22期

机译：TIPS-TTF作为低对称TTF衍生物的前体：TTF区域选择性C-H修饰中的立体保护策略
2. SYNTHESIS OF NEW MONO-FUNCTIONALISED TETRATHIAFULVALENE DERIVATIVES BY REACTIONS OF TETRATHIAFULVALENYLLITHIUM WITH ALDEHYDES AND KETONES - X-RAY CRYSTAL STRUCTURES OF TTF-CME(OH)FC, TTF-CME(OME)FC AND TTF-CH(OME)TTF (FC = FERROCENYL) [J] . Bryce MR., Moore AJ., Batsanov AS., Tetrahedron . 1997,第52期

机译：四硫杂戊醛酸锂与醛和酮的反应合成新的单官能的四硫杂富勒烯衍生物-TTF-CME（OH）FC，TTF-CME（OME）FC和TTF-CH（OMETT）的X射线晶体结构）
3. Chiral EDT-TTF precursors with one stereogenic centre: substituent size modulation of the conducting properties in the (R-EDT-TTF)(2)PF6 (R = Me or Et) series [J] . Mroweh Nabil, Auban-Senzier Pascale, Vanthuyne Nicolas, Journal of Materials Chemistry, C. materials for optical and electronic devices . 2019,第40期

机译：手性EDT-TTF前体具有一个立体中心：（R-EDT-TTF）（2）PF6（R = ME或ET）系列中的导电性能的取代尺寸调节
4. Regioselective Aromatic C-H Borylation Controlled by Remote Steric Effect [C] . Yutaro Saito, Yasutomo Segawa, Kenichiro Itami 日本化学会春季年会講演予稿集 . 2018

机译：通过远程空间效应控制的区域选择性芳香族C-H促进型
5. SYNTHESES, STRUCTURES, AND PROPERTIES OF NEW MULTI-CHALCOGEN TTF DERIVATIVES, THEIR CHARGE-TRANSFER COMPLEXES AND ION-RADICAL SALTS [D] . 中野, 英之 1991

机译：新型多卤代TTF衍生物，其电荷转移复合物和离子根盐的合成，结构和性质
6. Synthesis of racemic and chiral BEDT-TTF derivatives possessing hydroxy groups and their achiral and chiral charge transfer complexes [O] . Sara Jane Krivickas, Chiho Hashimoto, Junya Yoshida, 2015

机译：具有羟基的外消旋和手性BEDT-TTF衍生物的合成及其非手性和手性电荷转移复合物
7. Exo-methylene-BEDT-TTF and alkene-functionalised BEDT-TTF derivatives: synthesis and radical cation salts [O] . Zecchini, M, Lopez, JR, Allen, SW, 2015

机译：Exo-亚甲基-BEDT-TTF和烯烃官能化的BEDT-TTF衍生物：合成盐和自由基阳离子盐
8. Synthesis, Structure and Properties of BEDT-TTF Derivatives [R] . Nigrey, P. J. , Morosin, B. , Kwak, J. F. 1987

机译：BEDT-TTF衍生物的合成，结构与性质

TIPS-TTF as a precursor of low-symmetry TTF derivatives: Steric protection strategy in the regioselective C-H modification of TTF

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