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X-ray Structure of a Porphyrin–Tetramethylcucurbit[6]uril Supramolecular Polymer

机译:卟啉-四甲基葫芦[6]尿素超分子聚合物的X射线结构

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摘要

Supramolecular polymers, resulting from the combination of supramolecular chemistry and polymer science, are formed through directional and reversible non-covalent or dynamic covalent interactions among small-molecularweight monomers.~([1]) Associated with their novel features such as responsiveness to stimuli,~([2]) self-healing,~([3]) and degradability,~([ 4]) these supramolecular polymer materials have attracted increasing research interest due to their potential applications in the fields of photovoltaic devices,~([5]) drug delivery,~([ 6]) porous membranes,~([7]) and catalysts.~([8]) Starting from the first hydrogen bonding-based supramolecular polymer,~([9]) hydrogen bonding interactions,~([10]) strong π–π interactions,~([11]) and metal coordination~([12]) have been revealed to play an important role in the formation of supramolecular polymers due to their directionality and relative strength.
机译:超分子聚合物是由超分子化学和高分子科学相结合而形成的,是通过小分子单体之间的定向和可逆的非共价或动态共价相互作用而形成的。[[1])与诸如刺激, 〜([2])自修复,〜([3])和可降解性〜([4])这些超分子聚合物材料因其在光伏器件领域的潜在应用而吸引了越来越多的研究兴趣,〜([5 ])药物输送,〜([6])多孔膜,〜([7])和催化剂。〜([8])从第一个基于氢键的超分子聚合物开始,〜([9])氢键相互作用,由于它们的方向性和相对强度,〜([10])强烈的π-π相互作用〜([11])和金属配位〜([12])在超分子聚合物的形成中起着重要作用。

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