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首页> 外文期刊>Chemistry: A European journal >Energy-Transfer Properties of a [2.2]Paracyclophane-Based Through-Space Dimer
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Energy-Transfer Properties of a [2.2]Paracyclophane-Based Through-Space Dimer

机译：基于[2.2]环芳基的全空间二聚体的能量转移性质。

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摘要

Over the past three decades, much attention has been paid to conjugated oligomers and polymers because of their intriguing optoelectronic properties derived from their delocalized p-electrons along the conjugated polymer backbone. They are highly promising candidates for next-generation materials, because they possess the general advantages of organic polymers, such as film-forming properties, pro-cessability, and light weights in addition to light-emitting properties, liquid crystallinity, and conductivity. Almost all the conjugated polymers synthesized to date are through-bond-type conjugated polymers comprising sp and/ or sp~2 carbon frameworks. Through-space-type conjugated polymers, in which p-electron systems are stacked in close proximity in a single-polymer chain, have rarely been reported in spite of the importance of such p-stacked structures in optoelectronic devices.
机译：在过去的三十年中，共轭低聚物和聚合物引起了人们的极大关注，因为它们具有令人兴奋的光电特性，这些特性来自于沿共轭聚合物主链的离域p电子。它们是下一代材料的极有希望的候选者，因为它们除了发光性能，液晶性和导电性外，还具有有机聚合物的一般优势，例如成膜性，可加工性和重量轻。迄今为止，几乎所有合成的共轭聚合物都是包含sp和/或sp〜2碳骨架的键合型共轭聚合物。尽管在光电器件中这种p-堆叠结构很重要，但很少报道过其中p-电子系统紧密堆叠在单聚合物链中的穿空型共轭聚合物。

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