Monoester copillar[5]arenes: Synthesis, unusual self-inclusion behavior, and molecular recognition

Chen Y.; Cao D.; Wang L.; He M.; Zhou L.; Schollmeyer D.; Meier H.

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Monoester copillar[5]arenes: Synthesis, unusual self-inclusion behavior, and molecular recognition

机译：单酯copillar [5]芳烃：合成，异常的自包含行为和分子识别

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The self-inclusion behavior of monoester copillar[5]arenes depends on the position of the ester group, which causes different guest selectivities. Monoester copillar[5]arenes bearing an acetate chain can form stable self-inclusion complexes in low- and high-concentration solution and exhibit high guest selectivity. However, a monoester copillar[5]arene bearing a butyrate chain can not form a self-inclusion complex and exhibits low guest selectivity. Thus, a new class of stable self-inclusion complexes of copillar[5]arenes was explored to improve the selectivity of molecular recognition.

机译：单酯copillar [5]芳烃的自包含行为取决于酯基的位置，这会导致不同的客体选择性。带有乙酸酯链的单酯copillar [5]芳烃可以在低浓度和高浓度溶液中形成稳定的自包合物，并具有高的客体选择性。然而，带有丁酸酯链的单酯copillar [5]芳烃不能形成自包合物，并且表现出低的客体选择性。因此，探索了一类新的稳定的copillar [5]芳烃自包合物，以提高分子识别的选择性。

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《Chemistry: A European journal》 |2013年第22期|共7页
作者
Chen Y.; Cao D.; Wang L.; He M.; Zhou L.; Schollmeyer D.; Meier H.;
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正文语种 eng
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关键词
host-guest chemistry; inclusion compounds; molecular recognition; pillar5arenes;

机译：客体化学;包裹体化合物;分子识别;柱[5]芳烃;

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1. Monoester copillar[5]arenes: Synthesis, unusual self-inclusion behavior, and molecular recognition [J] . Chen Y., Cao D., Wang L., Chemistry: A European journal . 2013,第22期

机译：单酯copillar [5]芳烃：合成，异常的自包含行为和分子识别
2. Synthesis of Copillar5arene by Co-oligomerization of Different Monomers and Its Application to Supramolecular Polymer Gel [J] . Hui Li, Yuanrong Zhu, Bingbing Shi, 中国化学（英文版） . 2015,第003期

机译：不同单体的共聚反应制备Copillar 5芳烃及其在超分子聚合物凝胶中的应用
3. Synthesis of diverse N, O-bridged calix[1]arene[4]pyridine-C_(60) dyads and triads and formation of intramolecular self-inclusion complexes [J] . Wu J.-C., Wang D.-X., Huang Z.-T., The Journal of Organic Chemistry . 2010,第24期

机译：多种N，O-桥杂杯[1]芳烃[4]吡啶-C_（60）二元和三元化合物的合成及分子内自包合物的形成
4. Dynamic Molecular Tweezers with Tetrathiafulvalene Arms: Synthesis, Conformational Behavior, and Molecular Recognition Properties [C] . Vladimir A. Azov, Rafael Gomez, Macej Skibinski European Symposium on Organic Chemistry . 2009

机译：带有四渐次valene臂的动态分子镊子：合成，构象行为和分子识别性能
5. Synthesis of small molecules with specific function: I. Peptidocalix[4]arenes as molecular receptors. II. Towards the total synthesis of (-)-dihydroguaiaretic acid. [D] . Brewster, Rachel Elizabeth. 2004

机译：具有特定功能的小分子的合成：I.肽杯[4]芳烃作为分子受体。二。致力于（-）-二氢愈创木酸的全合成。
6. Synthesis of deep-cavity fluorous calix4arenes as molecular recognition scaffolds [O] . Maksim Osipov, Qianli Chu, Steven J Geib, 2008

机译：深腔氟杯4芳烃的合成作为分子识别支架
7. Synthesis of 9,10-Bis-ketoenaminoanthryl and 9,10-Bis-isoxazolylanthryl Linked Biscalix4arenes: Atropisomers and Molecular Recognitions [O] . Chia-Chen Tsai, I-Ting Ho, Jean-Ho Chu, 2012

机译：9,10-双酮氨基氨基蒽基和9,10-双isoxazolylanthryl连接的BESCALIX 4 areNes：取婚体和分子识别

Monoester copillar[5]arenes: Synthesis, unusual self-inclusion behavior, and molecular recognition

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