Ligand–Metal Cooperating PC(sp~3)P Pincer Complexes as Catalysts in Olefin Hydroformylation

Sanaa Musa; Oleg A. Filippov; Natalia V. Belkova; Elena S. Shubina; Gleb A. Silantyev; Lutz Ackermann; Dmitri Gelman

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Ligand–Metal Cooperating PC(sp~3)P Pincer Complexes as Catalysts in Olefin Hydroformylation

机译：配体-金属配合物PC（sp〜3）P钳配合物在烯烃加氢甲酰化反应中的催化作用

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In recent years, metal complexes, in which both the metal center and the ligand play active and cooperative roles, have emerged as very promising catalysts, capable of activating and forming chemical bonds through nonoxidative pathways (i.e., alternative to the conventional oxidative addition/reductive elimination sequence). The key mechanistic steps usually include a reversible switching between the coordination modes of the ligands that are bound to the catalytically active metal center (Scheme 1).

机译：近年来，金属中心和配体都起着积极和协同作用的金属络合物已经成为非常有前途的催化剂，能够通过非氧化途径活化和形成化学键（例如，替代传统的氧化加/还原反应）消除顺序）。关键的机械步骤通常包括与催化活性金属中心结合的配体配位模式之间的可逆转换（方案1）。

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《Chemistry: A European journal》 |2013年第50期|共4页
作者
Sanaa Musa; Oleg A. Filippov; Natalia V. Belkova; Elena S. Shubina; Gleb A. Silantyev; Lutz Ackermann; Dmitri Gelman;
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正文语种 eng
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complexes; through; oxidative;

机译：配合物;通过;氧化;

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1. Ligand–Metal Cooperating PC(sp~3)P Pincer Complexes as Catalysts in Olefin Hydroformylation [J] . Sanaa Musa, Oleg A. Filippov, Natalia V. Belkova, Chemistry: A European journal . 2013,第50期

机译：配体-金属配合物PC（sp〜3）P钳配合物在烯烃加氢甲酰化反应中的催化作用
2. Different Coordination Modes of the (Ph2PCspPPh2)-P-3 Pincer Ligand in Rhodium Complexes as a Consequence of C-sp(3)-H Metal Interaction [J] . Arras Janet, Speth Hansjoerg, Mayer Hermann A., Organometallics . 2015,第14期

机译：（Ph2PCspPPh2）-P-3钳配体在铑配合物中的不同配位模式，作为C-sp（3）-H金属相互作用的结果
3. New possible mode of ligand-metal cooperation in PC(sp~3)P pincer complexes [J] . Musa S., Romm R., Azerraf C., Dalton transactions: An international journal of inorganic chemistry . 2011,第35期

机译：PC（sp〜3）P钳配合物中配体-金属配合的新可能模式
4. Synthesis and Structure of Monoalkyl Complexes of Group 4 Metal Bearing Aminopyrrole Ligand and Their Application for Olefin Polymerization Catalyst [C] . Takahiro Yasumoto, Tsuneaki Yamagata, Kazushi Mashima Symposium on Organometallic Chemistry . 2006

机译：第4族金属亚氨基吡咯配体的单烷基复合物的合成与结构及其对烯烃聚合催化剂的应用
5. Bis(thiophenolate)pyridine Pincer Ligands and Trivalent Zirconocene Complexes Relevant to Early Transition Metal Polymerization Catalysts. [D] . Lenton, Taylor. 2014

机译：与早期过渡金属聚合催化剂有关的双（硫酚盐）吡啶钳配体和三价锆茂配合物。
6. Ligand survey results in identification of PNP pincer complexes of iridium as long-lived and chemoselective catalysts for dehydrogenative borylation of terminal alkynes [O] . Chun-I Lee, Jessica C. DeMott, Christopher J. Pell, 2015

机译：配体的调查结果可确定铱的PNP钳形配合物作为末端炔烃脱氢硼化的长寿命和化学选择性催化剂
7. Bis(thiophenolate)pyridine pincer ligands and trivalent zirconocene complexes relevant to early transition metal polymerization catalysts [O] . Lenton Taylor Nichole Baker 2014

机译：与早期过渡金属聚合催化剂相关的双（苯硫酚）吡啶钳形配体和三价锆茂配合物

Ligand–Metal Cooperating PC(sp~3)P Pincer Complexes as Catalysts in Olefin Hydroformylation

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