Primary-tertiary diamine/Br?nsted acid catalyzed C-C coupling between para-vinylanilines and aldehydes

Cui L.; Zhu Y.; Luo S.; Cheng J.-P.

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Primary-tertiary diamine/Br?nsted acid catalyzed C-C coupling between para-vinylanilines and aldehydes

机译：伯-叔二胺/布朗斯台德酸催化对乙烯基苯胺和醛之间的C-C偶联

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Aromatic enamines: para-Vinylanilines were identified as unique nucleophiles, closely resembling enamines, to undergo C-C coupling with aldehydes catalyzed by a simple primary-tertiary diamine/Br?nsted acid. The resulting bis(allylic) adducts, which have potential as functional materials, were obtained in high yields under rather mild conditions (see scheme).

机译：芳香烯胺：对乙烯基苯胺被确定为独特的亲核试剂，与烯胺极为相似，与简单的伯叔二胺/布朗斯台德酸催化的醛进行C-C偶联。在相当温和的条件下（参见方案）以高收率获得了具有潜力作为功能材料的双（烯丙基）加合物。

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《Chemistry: A European journal》 |2013年第29期|共4页
作者
Cui L.; Zhu Y.; Luo S.; Cheng J.-P.;
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正文语种 eng
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关键词
C-C bond formation; enamines; iminium activation; organocatalysis; primary amines;

机译：C-C键形成;烯胺;亚胺活化;有机催化;伯胺;

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专利

1. Primary-tertiary diamine/Br?nsted acid catalyzed C-C coupling between para-vinylanilines and aldehydes [J] . Cui L., Zhu Y., Luo S., Chemistry: A European journal . 2013,第29期

机译：伯-叔二胺/布朗斯台德酸催化对乙烯基苯胺和醛之间的C-C偶联
2. Primary-Tertiary Diamine/Brφnsted Acid Catalyzed α-Allylation of Carbonyl Compounds with Allylic Alcohols [J] . Lingyun Cui, Long Zhang, Sanzhong Luo, 中国化学（英文版） . 2014,第008期

机译：伯叔叔二胺/布朗斯台德酸催化烯丙基醇与羰基化合物的α-烯丙基化
3. A new chiral primary-tertiary diamine-Br?nsted acid salt organocatalyst for the highly enantioselective direct anti-aldol and syn-Mannich reactions [J] . Chen G., Fu X., Wu C., Research on Chemical Intermediates . 2013,第3期

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4. REACTION PATHWAYS AND CATALYTIC REQUIREMENTS FOR ALDEHYDE DEOXYGENATION ON SOLID BR0NSTED ACID CATALYSTS [C] . Fan Lin, Ya-Huei (Cathy) Chin ACS National Meeting Exhibition . 2014

机译：固体BR0Sted酸催化剂上醛脱氧的反应途径和催化要求
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机译：手性布朗斯台德酸催化对映体的对映选择性合成消旋动力学拆分醛丙炔基硼酸酯制备抗同炔丙基醇烯丙基硼酸酯
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机译：镍和Brønsted酸催化的氧化还原氧化氧 - 中性偶联1,3-二烯和醛合成丁烯酚

Primary-tertiary diamine/Br?nsted acid catalyzed C-C coupling between para-vinylanilines and aldehydes

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