New synthesis of A-ring aromatic strigolactone analogues and their evaluation as plant hormones in pea (pisum sativum)

Chen V.X.; Boyer F.-D.; Rameau C.; Pillot J.-P.; Vors J.-P.; Beau J.-M.

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New synthesis of A-ring aromatic strigolactone analogues and their evaluation as plant hormones in pea (pisum sativum)

机译：豌豆（Pisum sativum）中A环芳香族甾内酯类似物的新合成及其作为植物激素的评价

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A new general access to A-ring aromatic strigolactones, a new class of plant hormones, has been developed. The key transformations include in sequence ring-closing metathesis, enzymatic kinetic resolution and a radical cyclization with atom transfer to install the tricyclic ABC-ring system. The activity as plant hormones for the inhibition of shoot branching in pea of various analogues synthesized by this strategy is reported. Inhibiting shoot branching: A new general access to A-ring aromatic strigolactones (see scheme), a new class of plant hormones, has been developed. The biological activity of various analogues synthesized by this strategy for inhibiting bud outgrowth in pea was evaluated.

机译：已开发出一种新的普遍使用A环芳香族内酯的方法，这是一类新的植物激素。关键的转化包括顺序闭环复分解，酶促动力学拆分和带有原子转移的自由基环化反应，以安装三环ABC环系统。据报道，通过这种策略合成的各种类似物作为植物激素具有抑制豌豆芽分支的活性。抑制枝条分支：已经开发出一种新的普遍使用A环芳香族内酯的方法（参见方案），这是一类新的植物激素。评价了通过该策略合成的各种类似物的抑制豌豆芽生长的生物活性。

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来源
《Chemistry: A European journal》 |2013年第15期|共9页
作者
Chen V.X.; Boyer F.-D.; Rameau C.; Pillot J.-P.; Vors J.-P.; Beau J.-M.;
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正文语种 eng
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lactones; plant hormones; radical reactions; structure-activity relationships; total synthesis;

机译：内酯;植物激素;自由基反应;构效关系;总合成;

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专利

1. New synthesis of A-ring aromatic strigolactone analogues and their evaluation as plant hormones in pea (pisum sativum) [J] . Chen V.X., Boyer F.-D., Rameau C., Chemistry: A European journal . 2013,第15期

机译：豌豆（Pisum sativum）中A环芳香族甾内酯类似物的新合成及其作为植物激素的评价
2. GH3 expression and IAA-amide synthetase activity in pea (Pisum sativum L.) seedlings are regulated by light, plant hormones and auxinic herbicides. [J] . Ostrowski M., Jakubowska A. Journal of Plant Physiology . 2013,第4期

机译：豌豆（Pisum sativum L.）幼苗中的GH3表达和IAA-酰胺合成酶活性受光照，植物激素和植物生长素除草剂的调节。
3. The effect of cytokinins and other plant hormones on the growth of cotyledonary axilars of flax (Linum usitatissimum), sunflower (Helianthus annuus) and pea (Pisum sativum) [J] . Klicova S, Sebanek J, Vlasic T Plant, Soil and Environment . 2004,第4期

机译：细胞分裂素和其他植物激素对亚麻（Linum usitatissimum），向日葵（Helianthus annuus）和豌豆（Pisum sativum）的子叶轴生长的影响
4. Plant peptide hormone phytosulfokine (PSK):Synthesis of new analogues and their biological evaluation [C] . Agata Bahyrycz, Yoshikatsu Matsubayashi, Mari Ogawa, European Peptide Symposium . 2002

机译：植物肽激素植物植物霉素（PSK）：新类似物的合成及其生物学评价
5. Plant ‘integrin-like’ proteins in pea (Pisum sativum L.) embryonic axes [D] . Mo, Bing 2004

机译：在豌豆（Pisum sativum L.）的胚轴中种植“整合素样”蛋白
6. Anatomy and Histochemistry of Seed Coat Development of Wild (Pisum sativum subsp. elatius (M. Bieb.) Asch. et Graebn. and Domesticated Pea (Pisum sativum subsp. sativum L.) [O] . Lenka Zablatzká, Jana Balarynová, Barbora Klčová, 2021

机译：野生种子涂层的解剖学和组织化学（Pisum Sativum subsp。Elatius（M. bieb。）asch。et graebn。和驯养的豌豆（pisum sativum subsp。sativum l.）
7. Evaluation of native Rhizobium leguminosarum bv. viceae of pea plants (Pisum sativum L.) for nodulation efficiency and yield promotion in lentil crop (Lens culnaris Medik.) under acid soil [O] . Christy ., B. K. Sangma, Dwipendra Thakuria 2018

机译：对天然根茎豆科植物的评价。豌豆植物（Pisum sativum L.）的植物植物豆荚效率和产量促进在酸性土壤下的豆类作物（镜片Culnaris Medik。）

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New synthesis of A-ring aromatic strigolactone analogues and their evaluation as plant hormones in pea (pisum sativum)

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