Punching a Carbon Atom of C_(60) into its Own Cavity to Form an Endohedral Complex CO@C_(59)O_6 under Mild Conditions

Lijun Shi; Dazhi Yang; Francesca Colombo; Yuming Yu; Wen-Xiong Zhang; Liangbing Gan

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Punching a Carbon Atom of C_(60) into its Own Cavity to Form an Endohedral Complex CO@C_(59)O_6 under Mild Conditions

机译：在温和条件下将C_（60）的碳原子冲入其自身的腔中以形成内表面复合体CO @ C_（59）O_6

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In conclusion, the formation of compound 5 from compound 3 shows that covalent chemistry of fullerene can serve as a soft method for the deletion and trapping of a fullerene skeleton atom. The oxidative cleavage of three adjacent double bonds around the same pentagon of C_(60) is reminiscent of the longitudinal unzipping of SWCNTs (single wall carbon nanotubes) by KMnO_4/H_2SO_4 into graphene nanoribbons. The present results indicate a strong tendency for the empty cavity in fullerenes to attract a guest to form endohedral complexes. Chemical synthesis of other endohedral fullerenes should be feasible by using suitable precursors.

机译：总之，由化合物3形成的化合物5表明，富勒烯的共价化学可作为富勒烯骨架原子的缺失和俘获的软方法。 C_（60）的同一五边形周围的三个相邻双键的氧化裂解使人想起了KMnO_4 / H_2SO_4将SWCNTs（单壁碳纳米管）纵向解压缩为石墨烯纳米带。目前的结果表明富勒烯中的空洞有很强的吸引客体形成内面复合体的趋势。通过使用合适的前体，化学合成其他内层富勒烯应该是可行的。

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《Chemistry: A European journal》 |2013年第49期|共5页
作者
Lijun Shi; Dazhi Yang; Francesca Colombo; Yuming Yu; Wen-Xiong Zhang; Liangbing Gan;
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正文语种 eng
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carbon monoxide; endohedral fullerene; heterofullerene; open-cage fullerene; peroxide;

机译：一氧化碳;内表面富勒烯;杂富勒烯;开笼富勒烯;过氧化物;

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1. Punching a Carbon Atom of C_(60) into its Own Cavity to Form an Endohedral Complex CO@C_(59)O_6 under Mild Conditions [J] . Lijun Shi, Dazhi Yang, Francesca Colombo, Chemistry: A European journal . 2013,第49期

机译：在温和条件下将C_（60）的碳原子冲入其自身的腔中以形成内表面复合体CO @ C_（59）O_6
2. Interaction between the alkali atoms and the C_(60), cage in the endohedral complexes (Alkali @C_(60)) [J] . ZHU Chuanbao, YAN Jimin Chinese science bulletin . 1995,第21期

机译：内原子络合物中碱原子与C_（60）笼的相互作用（碱@C_（60））
3. Response to external GHz and THz radiation of K~+@C_(60) endohedral complex in cavity of carbon nanotube containing polymerized fullerenes [J] . Slepchenkov Michael M., Shunaev Vladislav V., Glukhova Olga E. Journal of Applied Physics . 2019,第24期

机译：含聚合富勒烯的碳纳米管腔中K〜+ @ C_（60）内表面复合物对外部GHz和THz辐射的响应
4. DFT study of endohedral complexes of group V atoms with C_(60) [C] . Akshu Pahuja, Sunita Srivastava International Conference on Advances in Condensed and Nano Materials . 2011

机译：v原子与C_（60）的v原子腹腔复合物的DFT研究
5. I. Tertiary aryl sulfonamides as new cross coupling partners for nickel catalyzed Kumada-Corriu-Tamao reductive and carbon-carbon bond forming cross coupling reactions. II. N-sulfonyl deprotection under mild nickel(0) catalyzed Kumada-Corriu-Tamao coupling conditions and development of the N-Ans protecting group. III. Synthesis and application of 3,3'-di-(2-pyridyl)-1,1'-bi-2-naphthol ligands [D] . Milburn, Robert Ronald 2004

机译：I.叔芳基磺酰胺作为镍催化的Kumada-Corriu-Tamao还原和碳-碳键形成交叉偶联反应的新交叉偶联伴侣。二。在温和的镍（0）下N-磺酰基脱保护催化了Kumada-Corriu-Tamao偶联条件和N-Ans保护基的发展。三， 3,3'-二-（2-吡啶基）-1,1'-bi-2-萘酚配体的合成及应用
6. Single rhodium atoms anchored in micropores for efficient transformation of methane under mild conditions [O] . Yu Tang, Yuting Li, Victor Fung, -1

机译：铑原子固定在微孔中可在温和条件下有效转化甲烷
7. The threshold displacement energy of buckminsterfullerene C60 and formation of the endohedral defect fullerene He@C59 [O] . Mark H. Stockett, Michael Wolf, Michael Gatchell, 2018

机译：Caketminsterfullerene C60的阈值位移能量和Endohedral缺陷富勒烯的形成He @ C59

Punching a Carbon Atom of C_(60) into its Own Cavity to Form an Endohedral Complex CO@C_(59)O_6 under Mild Conditions

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