Enantiospecific, Regioselective Cross-Coupling Reactions of Secondary Allylic Boronic Esters

Laetitia Chausset-Boissarie; Kazem Ghozati; Emily LaBine; Jack L.-Y. Chen; Varinder K. Aggarwal; Cathleen M. Crudden

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Enantiospecific, Regioselective Cross-Coupling Reactions of Secondary Allylic Boronic Esters

机译：仲烯丙基硼酸酯的对映体特异性，区域选择性交叉偶联反应

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Asymmetric cross-coupling reactions in which stereochemistry-bearing C-C bonds are created are still in their infancy. Considering the wealth of compounds that can be prepared by cross-coupling methodologies, and the importance of synthetic methods leading to enantiomerically enriched products, this is a surprising reality. Advances in this area have occurred in the past few years, in the realm of enantioselective or enantiospecific cross-couplings of chiral electrophiles.

机译：带有立体化学的C-C键的不对称交叉偶联反应仍处于起步阶段。考虑到可以通过交叉偶联方法制备的大量化合物，以及导致对映体富集的产品的合成方法的重要性，这是一个令人惊讶的现实。在过去的几年中，在手性亲电试剂的对映选择性或对映特异性交叉偶联领域中已经取得了进展。

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《Chemistry: A European journal》 |2013年第52期|共4页
作者
Laetitia Chausset-Boissarie; Kazem Ghozati; Emily LaBine; Jack L.-Y. Chen; Varinder K. Aggarwal; Cathleen M. Crudden;
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正文语种 eng
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reactions; cross; bonds;

机译：反应;交叉;键;

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1. Enantiospecific, Regioselective Cross-Coupling Reactions of Secondary Allylic Boronic Esters [J] . Laetitia Chausset-Boissarie, Kazem Ghozati, Emily LaBine, Chemistry: A European journal . 2013,第52期

机译：仲烯丙基硼酸酯的对映体特异性，区域选择性交叉偶联反应
2. Suzuki-Miyaura cross-couplings of secondary allylic boronic esters [J] . Ben W. Glasspoole, Kazem Ghozati, Jonathon W. Moir, Chemical Communications . 2012,第9期

机译：仲烯丙基硼酸酯的Suzuki-Miyaura交叉偶联
3. Hydroamination versus Allylic Amination in Iridium-Catalyzed Reactions of Allylic Acetates with Amines: 1,3-Aminoalcohols via Ester-Directed Regioselectivity [J] . SeungWook Kim, Thomas Wurm, Gilmar A. Brito, Journal of the American Chemical Society . 2018,第29期

机译：烯丙基乙酸与胺的铱催化反应中的氢化胺化与烯丙胺化反应：经由酯基区域选择性的1,3-氨基醇
4. Palladium-Catalyzed Regioselective Allylic Alkylation of Fluorine-Containing Allylic Esters [C] . Shohei Wada, Shuichi Hayase, Motoi Kawatsura Symposium on Organometallic Chemistry . 2006

机译：钯催化的含氟烯丙基酯的烯丙基烷基化烷基化
5. Enantiospecific, regioselective Suzuki-Miyaura cross-couplings of secondary, allylic boronic esters. [D] . LaBine, Emily Judith. 2014

机译：对映体，区域选择性的仲烯丙基硼酸酯的Suzuki-Miyaura交叉偶联。
6. Hydroamination versus Allylic Amination in Iridium Catalyzed Reactions of Allylic Acetates with Amines: 13-Aminoalcohols via Ester-Directed Regioselectivity [O] . Seung Wook Kim, Thomas Wurm, Gilmar A. Brito, -1

机译：铱催化烯丙乙酸酯与胺：13-氨基醇通过酯基定向区域选择性反应中的氢化胺化与烯丙胺化
7. Enantiospecific, Regioselective Cross-Coupling Reactions of Secondary Allylic Boronic Esters [O] . Chausset-Boissarie, Laetitia, Ghozati, Kazem, LaBine, Emily, 2013

机译：仲烯丙基硼酸酯的对映体特异性，区域选择性交叉偶联反应

Enantiospecific, Regioselective Cross-Coupling Reactions of Secondary Allylic Boronic Esters

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