首页> 外文期刊>Chemistry: A European journal >Ionic conductivity in the metal-organic framework UiO-66 by dehydration and insertion of lithium tert-butoxide
【24h】

Ionic conductivity in the metal-organic framework UiO-66 by dehydration and insertion of lithium tert-butoxide

机译:叔丁醇锂的脱水和插入作用在金属有机骨架UiO-66中的离子电导率

获取原文
获取原文并翻译 | 示例
           

摘要

Shields up! Post-synthetic modification of the secondary building units in the metal-organic framework UiO-66 (Zr_6O_4(OH) _4(O_2CR)_(12)) by dehydration and subsequent grafting of LiOtBu (see picture, green) yields a solid Li~+ electrolyte with a conductivity of 1.8×10~(-5)S cm~(-1) at 293K. As the grafting leads to screening of the anionic charge, the activation energy for ionic conduction is significantly lower than when Li~+ is introduced through deprotonation.
机译:屏蔽起来!在金属有机框架UiO-66(Zr_6O_4(OH)_4(O_2CR)_(12))中通过脱水和随后接枝LiOtBu的合成后修饰来生成固体Li〜 +在293K时电导率为1.8×10〜(-5)S cm〜(-1)的电解质。由于接枝导致阴离子电荷的筛选,离子传导的活化能明显低于通过去质子化引入Li〜+时的活化能。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号