Non-covalent activation of a titanium(IV) oxygen-transfer catalyst

Zonta C.; Licini G.

首页> 外文期刊>Chemistry: A European journal >Non-covalent activation of a titanium(IV) oxygen-transfer catalyst

【24h】

Non-covalent activation of a titanium(IV) oxygen-transfer catalyst

机译：钛（IV）氧转移催化剂的非共价活化

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Blame it on the alcohol: Kinetic studies, in combination with theoretical calculations, support a mechanism in which the coordination of one alcohol molecule activates a Ti~(IV) pre-catalyst (see scheme). The alcohol coordination has a twofold action: it switches the Ti~(VI) peroxo complex to an active geometry, and it stabilises the reactive peroxo intermediate through hydrogen bonding.

机译：怪罪于酒精：动力学研究与理论计算相结合，支持了一种机制，其中一个酒精分子的配位活化了Ti〜（IV）预催化剂（参见方案）。醇配位具有双重作用：将Ti〜（VI）过氧配合物转换为活性几何结构，并通过氢键稳定反应性过氧中间体。

著录项

来源
《Chemistry: A European journal》 |2013年第29期|共4页
作者
Zonta C.; Licini G.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词
catalysts; density functional calculations; homogeneous catalysis; oxidation; titanium;

机译：催化剂密度泛函计算均相催化氧化钛;

相似文献

外文文献
中文文献
专利

1. Non-covalent activation of a titanium(IV) oxygen-transfer catalyst [J] . Zonta C., Licini G. Chemistry: A European journal . 2013,第29期

机译：钛（IV）氧转移催化剂的非共价活化
2. Activation of a Bis-(Phenoxyimine) Titanium (IV) Catalyst Using Different Aluminoxane Co-Catalysts [J] . Dario Romano, Sara Ronca, Sanjay Rastogi Macromolecular symposia . 2015,第Null期

机译：使用不同的铝氧烷助催化剂活化双（苯氧基亚胺）钛（IV）催化剂
3. Aluminoxane co-catalysts for the activation of a bis phenoxyimine titanium (IV) catalyst in the synthesis of disentangled ultra-high molecular weight polyethylene [J] . Romano Dario, Andablo-Reyes Efren, Ronca Sara, Polymer: The International Journal for the Science and Technology of Polymers . 2015,第Null期

机译：铝氧烷助催化剂在解缠的超高分子量聚乙烯合成中活化双苯氧基亚胺钛（IV）催化剂
4. Activation of a Bis-(Phenoxyimine) Titanium (IV) Catalyst Using Different Aluminoxane Co-Catalysts [C] . Dario Romano, Sara Ronca, Sanjay Rastogi International conference on Polyolefin Characterization . 2015

机译：使用不同铝氧烷助催化剂的双（苯氧亚胺）钛（IV）催化剂的激活
5. Titanium(IV) oxide photocatalysts with palladium and surface acidity and photocatalytic activity of titanium(IV) oxide, tungsten(VI) oxide/titanium(IV) oxide, and molybdenum(VI) oxide/titanium(IV) oxide photocatalysts. [D] . Papp, Jennifer Ellen. 1994

机译：具有钯，表面酸度和氧化钛（IV），氧化钨（VI）/氧化钛（IV）和氧化钼（VI）/氧化钛（IV）的表面酸性和光催化活性的氧化钛（IV）光催化剂。
6. Effect of Vanadium(IV)-Doping on the Visible Light-Induced Catalytic Activity of Titanium Dioxide Catalysts for Methylene Blue Degradation [O] . Wen-Churng Lin, Yo-Jane Lin -1

机译：掺杂钒对可见光诱导的二氧化钛催化亚甲基蓝降解的催化活性
7. Aluminoxane co-catalysts for the activation of a bis phenoxyimine titanium (IV) catalyst in the synthesis of disentangled ultra-high molecular weight polyethylene [O] . Romano, Dario, Andablo-Reyes, Efren, Ronca, Sara, 2015

机译：铝氧烷助催化剂在解缠的超高分子量聚乙烯合成中活化双苯氧基亚胺钛（IV）催化剂
8. Activation of hydrous titanium oxide-supported catalysts for HYD (hydrogenation), HDS (hydrodesulfurization), and HDO (hydrodeoxygenation) reactions. [R] . Dosch, R. G., Stohl, F. V., Richardson, J. T. 1989

机译：用于HYD（氢化），HDs（加氢脱硫）和HDO（加氢脱氧）反应的水合氧化钛负载催化剂的活化。

Non-covalent activation of a titanium(IV) oxygen-transfer catalyst

摘要

著录项

相似文献

相关主题

期刊订阅