Solvent-Dependent Cation Exchange in Metal–Organic Frameworks

Carl K. Brozek; Luca Bellarosa; Tomohiro Soejima; Talia V. Clark; Núlria López; Mircea Dinc?

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Solvent-Dependent Cation Exchange in Metal–Organic Frameworks

机译：金属有机框架中溶剂依赖性阳离子交换

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We investigated which factors govern the critical steps of cation exchange in metal–organic frameworks by studying the effect of various solvents on the insertion of Ni~(2+) into MOF-5 and Co~(2+) into MFU-4l. After plotting the extent of cation insertion versus different solvent parameters, trends emerge that offer insight into the exchange processes for both systems. This approach establishes a method for understanding critical aspects of cation exchange in different MOFs and other materials.

机译：通过研究各种溶剂对Ni〜（2+）插入MOF-5和Co〜（2+）插入MFU-4l的影响，我们研究了哪些因素控制金属有机框架中阳离子交换的关键步骤。在绘制了阳离子插入程度与不同溶剂参数的关系图之后，出现了一些趋势，可以深入了解两种系统的交换过程。该方法建立了一种理解不同MOF和其他材料中阳离子交换关键方面的方法。

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《Chemistry: A European journal》 |2014年第23期|共4页
作者
Carl K. Brozek; Luca Bellarosa; Tomohiro Soejima; Talia V. Clark; Núlria López; Mircea Dinc?;
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正文语种 eng
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关键词
cation exchange; ligand field parameters; metal–organic frameworks; polarity index; solvation energy;

机译：阳离子交换;配体场参数;金属有机骨架;极性指数;溶剂能;

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1. Solvent-Dependent Cation Exchange in Metal–Organic Frameworks [J] . Carl K. Brozek, Luca Bellarosa, Tomohiro Soejima, Chemistry: A European journal . 2014,第23期

机译：金属有机框架中溶剂依赖性阳离子交换
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机译：用阳离子交换金属 - 有机骨架催化二氧化碳固定二氧化碳
3. Density Functional Theory Computational Study of Alkali Cation-Exchanged Sodalite-like Zeolite like Metal-Organic Framework for CO2, N-2, and CH4 Adsorption [J] . Shang Jin, Li Gang, Li Jiaye, The journal of physical chemistry, C. Nanomaterials and interfaces . 2015,第49期

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4. Ionic Liquid/Metal-Organic Framework Hybrid Generated by Ion-Exchange Reaction: Synthesis and Unique Catalytic Activity [C] . Yohei Takashima, Mai Yokoyama, Takaaki Tsuruoka 日本化学会春季年会講演予稿集 . 2018

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6. Metal–Organic Framework-Derived Strategy forImproving Catalytic Performance of a Chromia-Based Catalyst in theChlorine/Fluorine Exchange Reactions for Unsaturated Fluorocarbons [O] . Xiutao Li, Haijun Zhang, Junyu Qiao, 2020

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Solvent-Dependent Cation Exchange in Metal–Organic Frameworks

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