Structures and Unexpected Dynamic Properties of Phosphine Oxides Adsorbed on Silica Surfaces

Hilliard Casie R.; Kharel Sugam; Cluff Kyle J.; Bhuvanesh Nattamai; Gladysz John A.; Bluemel Janet

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Structures and Unexpected Dynamic Properties of Phosphine Oxides Adsorbed on Silica Surfaces

机译：二氧化硅表面吸附的氧化膦的结构和意外的动力学性质

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Solid-state NMR spectroscopy of selected phosphine oxides adsorbed on silica surfaces establishes the surface mobilities, even of phosphine oxides with high melting points. Crystal structures of the adducts Ph3PO center dot HOSiPh3 and Cy3PO center dot H2O indicate that the interactions with silica involve hydrogen bonding of the P=O group to adsorbed water and surface silanol groups.

机译：选定的氧化膦吸附在二氧化硅表面上的固态NMR光谱确定了表面迁移率，甚至具有高熔点的氧化膦也是如此。加合物Ph 3 PO中心点HOSiPh 3和Cy 3 PO中心点H 2 O的晶体结构表明，与二氧化硅的相互作用涉及P ＝ O基团与吸附的水和表面硅烷醇基团的氢键键合。

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《Chemistry: A European journal》 |2014年第52期|共4页
作者
Hilliard Casie R.; Kharel Sugam; Cluff Kyle J.; Bhuvanesh Nattamai; Gladysz John A.; Bluemel Janet;
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正文语种 eng
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adsorbed phosphine oxides; silica; solid-state NMR spectroscopy; surface chemistry;

机译：吸附的氧化膦;二氧化硅;固态NMR光谱;表面化学;

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1. Structures and Unexpected Dynamic Properties of Phosphine Oxides Adsorbed on Silica Surfaces [J] . Hilliard Casie R., Kharel Sugam, Cluff Kyle J., Chemistry: A European journal . 2014,第52期

机译：二氧化硅表面吸附的氧化膦的结构和意外的动力学性质
2. Relationship between monolayer structure and dynamic surface properties of alkyl dimethyl phosphine oxides. BAM studies [J] . D. O. Grigoriev, O. Senkel, G. Kretzschmar, Colloids and Surfaces, A. Physicochemical and Engineering Aspects . 1999,第1a3期

机译：烷基二甲基氧化膦的单层结构与动态表面性能之间的关系。 BAM研究
3. Interfacial Properties of Tridecyl Dimethyl Phosphine Oxide Adsorbed at the Surface of a Solution Drop in Hexane Saturated Air [J] . Valentin B. Fainerman, Eugene V. Aksenenko, Alexander V. Makievski, Colloids and Interfaces . 2020,第2期

机译：在己烷饱和空气中溶液下降表面吸附的三乙二烷基二甲基氧化膦的界面性质
4. The Molecular Structures and Properties of Novel Eu(III) Complexes with Asymmetric Bis-Phosphine Oxides [C] . Hiroki Iwanaga, Fumihiko Aiga, Akio Amano Materials Research Society Symposium on Organic Electronics . 2006

机译：具有不对称双膦氧化物的新型EU（III）配合物的分子结构和性质
5. (31)P MAS NMR investigation of surface acidity on silica-alumina catalysts using adsorbed phosphines as new probes [D] . Hu, Bing 1997

机译：使用吸附的膦作为新探针的（31）P MAS NMR研究二氧化硅-氧化铝催化剂上的表面酸度
6. Development of Solid SEDDS IV: Effect of Adsorbed Lipid and Surfactant on Tableting Properties and Surface Structures of Different Silicates [O] . Suhas G. Gumaste, Sara A. Pawlak, Damon M. Dalrymple, -1

机译：固体SEDDS的开发IV：吸附的脂质和表面活性剂对不同硅酸盐的压片性能和表面结构的影响
7. Structures and Dynamics of Secondary and Tertiary Alkylphosphine Oxides Adsorbed on Silica [O] . Sugam Kharel, Kyle J. Cluff, Nattamai Bhuvanesh, 2019

机译：二氧化硅吸附二级和叔烷基膦氧化物的结构和动力学
8. Synthesis, Structure, and Properties of Poly(dimethylsiloxane) NetworksReinforced by in Situ-Precipitated Silica-Titania, Silica-Zirconia, and Silica-Alumina Mixed Oxides [R] . Wen, J., Mark, J. E. 1995

机译：原位沉淀二氧化硅 - 二氧化钛，二氧化硅 - 氧化锆和二氧化硅 - 氧化铝复合氧化物增强聚（二甲基硅氧烷）网络的合成，结构和性质

Structures and Unexpected Dynamic Properties of Phosphine Oxides Adsorbed on Silica Surfaces

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