Synthesis of New Lipid-Inspired Ionic Liquids by Thiol-ene Chemistry: Profound Solvent Effect on Reaction Pathway

Arsalan Mirjafari; Richard A. OBrien; Kevin N. West; James H. Davis Jr.

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Synthesis of New Lipid-Inspired Ionic Liquids by Thiol-ene Chemistry: Profound Solvent Effect on Reaction Pathway

机译：硫醇化学合成新型脂类启发离子液体：溶剂对反应途径的深刻影响

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The synthesis of a series of new lipid-inspired ionic liquids through thiol-ene "click" reaction with a single-step process. This synthesis offers considerable promise as an efficient and orthogonal method to construct structurally diverse imidazolium-type ionic liquids with linear and branched cationic tails, as well as versatility in the placement of the sulfur heteroatom. Profound solvent effect in this ene reaction regioselectivity has been observed.

机译：通过一步一步的硫醇-烯“点击”反应合成一系列新型的脂类启发性离子液体。这种合成方法作为一种有效且正交的方法，可用于构建结构多样的具有线性和支链阳离子尾部的咪唑类离子液体以及硫杂原子放置的通用性提供了可观的前景。已经观察到该烯反应区域选择性中的深刻的溶剂作用。

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《Chemistry: A European journal》 |2014年第25期|共5页
作者
Arsalan Mirjafari; Richard A. OBrien; Kevin N. West; James H. Davis Jr.;
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正文语种 eng
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关键词
biomaterials; click chemistry; ionic liquids; lipids; solvent effects;

机译：生物材料;点击化学;离子液体;脂质;溶剂效应;

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1. Synthesis of New Lipid-Inspired Ionic Liquids by Thiol-ene Chemistry: Profound Solvent Effect on Reaction Pathway [J] . Arsalan Mirjafari, Richard A. OBrien, Kevin N. West, Chemistry: A European journal . 2014,第25期

机译：硫醇化学合成新型脂类启发离子液体：溶剂对反应途径的深刻影响
2. Functionalized ionic liquids with highly polar polyhydroxylated appendages and their rapid synthesis via thiol-ene click chemistry [J] . Richard A. OBrien, Arsalan Mirjafari, Vijayakumari Jajam Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2011,第40期

机译：具有高极性多羟基附件的功能化离子液体及其通过硫醇-烯点击化学的快速合成
3. Chiral ionic liquids, a renewal for the chemistry of chiral solvents? Design, synthesis and applications for chiral recognition and asymmetric synthesis [J] . Baudequin C, Bregeon D, Levillain J, Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2005,第24期

机译：手性离子液体，手性溶剂化学的更新？手性识别和不对称合成的设计，合成及应用
4. "Click" Synthesis of Mercaptosilyl-Functionalized Ionic Liquids via Thiol-Ene Chemistry for Use as Hydrophobic Surface Coating Agents [C] . M. Sanchez Zayas, S. T. Nestor, J. C. Gaitor, PRiME Joint International Meeting of the Electrochemical Society, the Electrochemical Society of Japan, and the Korean Electrochemical Society . 2016

机译：通过硫醇-NEE化学合成巯基甲硅烷基官能化离子液体，用作疏水性表面涂层剂
5. Polar ionic media and stabilized charged species in organic synthesis: Ionic liquids derived from a biorenewable source, D-fructose, as a possible alternative to conventional organic reaction solvents. [D] . Okello, Maurice O. 2004

机译：有机合成中的极性离子介质和稳定的带电物种：来源于生物可再生来源D-果糖的离子液体，可以作为常规有机反应溶剂的替代方法。
6. Effects of a Protic Ionic Liquid on the Reaction Pathway during Non-Aqueous Sol–Gel Synthesis of Silica: A Raman Spectroscopic Investigation [O] . Anna Martinelli 2014

机译：质子离子液体对二氧化硅非水溶胶-凝胶合成过程中反应路径的影响：拉曼光谱研究
7. Novel Chloroimidazolium‐Based Ionic Liquids: Synthesis, Characterisation and Behaviour as Solvents to Control Reaction Outcome [O] . Rebecca R. Hawker, Janjira Panchompoo, Leigh Aldous, 2016

机译：基于新的氯咪唑鎓离子液体：合成，表征和行为作为控制反应结果的溶剂

Synthesis of New Lipid-Inspired Ionic Liquids by Thiol-ene Chemistry: Profound Solvent Effect on Reaction Pathway

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