Development of a Ruthenium/Phosphite Catalyst System for Domino Hydroformylation–Reduction of Olefins with Carbon Dioxide

Qiang Liu; Lipeng Wu; Ivana Fleischer; Detlef Selent; Robert Franke; Ralf Jackstell; Matthias Beller

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Development of a Ruthenium/Phosphite Catalyst System for Domino Hydroformylation–Reduction of Olefins with Carbon Dioxide

机译：用于多米诺加氢甲酰化的钌/亚磷酸盐催化剂体系的开发-用二氧化碳还原烯烃

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An efficient domino ruthenium-catalyzed reverse water-gas-shift (RWGS)-hydroformylation-reduction reaction of olefins to alcohols is reported. Key to success is the use of specific bulky phosphite ligands and triruthenium dodecacarbonyl as the catalyst. Compared to the known ruthenium/ chloride system, the new catalyst allows for a more efficient hydrohydroxymethylation of terminal and internal olefins with carbon dioxide at lower temperature. Unwanted hydrogenation of the substrate is prevented. Preliminary mechanism investigations uncovered the homogeneous nature of the active catalyst and the influence of the ligand and additive in individual steps of the reaction sequence.

机译：报道了烯烃对醇的有效多米诺钌催化的反向水煤气变换（RWGS）-加氢甲酰化-还原反应。成功的关键是使用特定的笨重的亚磷酸酯配体和十二碳三钌作为催化剂。与已知的钌/氯化物体系相比，这种新型催化剂可以在较低温度下用二氧化碳更有效地对末端和内部烯烃进行羟羟甲基化。防止了底物的有害氢化。初步的机理研究揭示了活性催化剂的均相性质以及配体和添加剂在反应顺序的各个步骤中的影响。

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《Chemistry: A European journal》 |2014年第23期|共7页
作者
Qiang Liu; Lipeng Wu; Ivana Fleischer; Detlef Selent; Robert Franke; Ralf Jackstell; Matthias Beller;
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正文语种 eng
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alkenes; carbon dioxide; hydroformylation; phosphite; ruthenium;

机译：烯烃;二氧化碳;羰基化;亚磷酸酯;钌;

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1. Development of a Ruthenium/Phosphite Catalyst System for Domino Hydroformylation–Reduction of Olefins with Carbon Dioxide [J] . Qiang Liu, Lipeng Wu, Ivana Fleischer, Chemistry: A European journal . 2014,第23期

机译：用于多米诺加氢甲酰化的钌/亚磷酸盐催化剂体系的开发-用二氧化碳还原烯烃
2. Hydroformylation of higher olefins by rhodium/tris((1H,1H,2H,2H-perfluorodecyl)phenyl)phosphites complexes in a fluorocarbon/hydrocarbon biphasic medium: effects of fluorinated groups on the activity and stability of the catalytic system [J] . Mathivet T., Monflier E., Castanet Y., Tetrahedron . 2002,第20期

机译：在碳氟烃/烃双相介质中，铑/三（（1H，1H，2H，2H-全氟癸基）苯基）亚磷酸酯络合物将高级烯烃加氢甲酰化：氟化基团对催化体系活性和稳定性的影响
3. Polyether phosphite for hydroformylation of higher olefins in non-aqueous system and catalyst recovery [J] . Liu XZ., Li HM., Wang YH., Journal of Organometallic Chemistry . 2002,第1a2期

机译：在非水体系中用于高级烯烃加氢甲酰化的聚亚磷酸酯和催化剂的回收
4. KINETICS OF HYDROFORMYLATION OF HIGHER OLEFINS USING RHODIUM-PHOSPHITE CATALYST IN A THERMOMORPHIC SOLVENT SYSTEM [C] . Maizatul S. Shaharun, Hilmi Mukhtar, Suzana Yusup American Institute of Chemical Engineers Annual Meeting . 2008

机译：磷酸盐催化剂在热晶体溶剂系统中使用铑 - 亚磷酸盐催化剂加氢甲酰化的动力学
5. Development of heterogeneous catalysts for hydroformylation of 1-hexene in supercritical carbon dioxide. [D] . Marteel, Anne Eugenie. 2003

机译：开发用于在超临界二氧化碳中1-己烯加氢甲酰化的非均相催化剂。
6. Hydroformylation of Cyclohexene with Carbon Dioxide and Hydrogen Using Ruthenium Carbonyl Catalyst: Influence of Pressures of Gaseous Components [O] . Shin-ichiro Fujita, Shuhei Okamura, Yoshinari Akiyama, 2007

机译：钌羰基催化剂与二氧化碳和氢气将环己烯加氢甲酰化：气态组分压力的影响
7. Development of a Ruthenium/Phosphite Catalyst System for Domino Hydroformylation-Reduction of Olefins with Carbon Dioxide [O] . Qiang Liu, Lipeng Wu, Ivana Fleischer, 2014

机译：用二氧化碳的Domino加氢甲酰化还原烯内加氢甲酰化还原的钌/亚磷酸盐催化剂体系
8. Research and development program for a combined carbon dioxide removal and reduction system. Supplement 1, phase 2a - Physicochemical properties of lithium chloride lithium carbonate melt mixtures [R] . Bockris, J. O., Calandra, A., Solomons, C. 1969

机译：二氧化碳联合去除和减少系统的研究和开发计划。补充1，阶段2a-氯化锂碳酸锂熔体混合物的物理化学性质

Development of a Ruthenium/Phosphite Catalyst System for Domino Hydroformylation–Reduction of Olefins with Carbon Dioxide

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