Cluster Size Effects of Platinum Oxide as Active Sites in Hydrogen Evolution Reactions

Yu Hang Li; Jun Xing; Xiao Hua Yang; Hua Gui Yang

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Cluster Size Effects of Platinum Oxide as Active Sites in Hydrogen Evolution Reactions

机译：氢氧化反应中作为活性位的氧化铂的簇大小效应

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The successful design of photocatalytic hydrogen generation from water relies on a thorough understanding of the role of cocatalyst. The photoreactivity was studied as a function of the cluster size of the oxidized platinum cocatalyst. The maximum turnover frequency is found on the smallest-sized cocatalyst. This effect can be attributed to the size-dependent proton adsorption.

机译：从水中成功产生光催化氢的设计取决于对助催化剂作用的透彻理解。研究了光反应性与氧化铂助催化剂簇尺寸的关系。在最小尺寸的助催化剂上可以找到最大的转换频率。这种作用可以归因于与尺寸有关的质子吸附。

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《Chemistry: A European journal》 |2014年第39期|共4页
作者
Yu Hang Li; Jun Xing; Xiao Hua Yang; Hua Gui Yang;
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正文语种 eng
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cluster size effects; heterogeneous catalysis; hydrogen; photocatalysis; platinum oxide;

机译：团簇尺寸效应;非均相催化;氢;光催化;氧化铂;

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1. Cluster Size Effects of Platinum Oxide as Active Sites in Hydrogen Evolution Reactions [J] . Yu Hang Li, Jun Xing, Xiao Hua Yang, Chemistry: A European journal . 2014,第39期

机译：氢氧化反应中作为活性位的氧化铂的簇大小效应
2. On the Availability of Active Sites for the Hydrogen Peroxide and Oxygen Reduction Reactions on Highly Dispersed Platinum Nanoparticles [J] . Timperman Laure, Luo Yun, Alonso-Vante Nicolas ChemElectroChem . 2016,第10期

机译：高度分散的铂纳米粒子上过氧化氢和氧还原反应的活性位点的可用性
3. Design principles for platinum nanoparticles catalysing electrochemical hydrogen evolution and oxidation reactions: edges are much more active than facets [J] . Zalitis C. M., Kucernak A. R., Sharman J., Journal of Materials Chemistry, A. Materials for energy and sustainability . 2017,第44期

机译：铂纳米粒子催化电化学氢气进化和氧化反应的设计原理：边缘比小平面更有效
4. Study on the active sulfur site of thiomolybdate clusters on carbon nanotubes for hydrogen evolution reaction [C] . Cheol-Ho Lee, Han-Ik Joh, Sungho Lee World Conference on Carbon . 2020

机译：氢化反应碳纳米管中硫钼簇簇活性硫位点的研究
5. METAL ATOM REACTIVITY PATTERNS: THE REACTIONS OF METAL ATOMS WITH ACETONE, ZIRCONIUM ATOMS WITH ALKYLBENZENES, AND PLATINUM ATOMS AS ACTIVE SITES IN HETEROGENEOUS CATALYSTS (ELECTROMOTIVE FORCE, HYDROGENATION, ARENES, OLEFINS) [D] . ROSS, JEFFREY SCOTT 1986

机译：金属原子反应性模式：非均相催化剂中金属原子与丙酮，锆原子与烷基苯和铂原子作为活性位点的反应（电势，加氢，芳烃，烯烃）
6. Universal dependence of hydrogen oxidation and evolution reaction activity of platinum-group metals on pH and hydrogen binding energy [O] . Jie Zheng, Wenchao Sheng, Zhongbin Zhuang, 2016

机译：氢氧化和铂族金属的析出反应活性对pH和氢结合能的普遍依赖性
7. Design principles for platinum nanoparticles catalysing electrochemical hydrogen evolution and oxidation reactions: edges are much more active than facets [O] . Zalitis, C, Kucernak, ARJ, Sharman, J, 2017

机译：铂纳米粒子催化电化学析氢和氧化反应的设计原则：边缘比刻面更活跃

Cluster Size Effects of Platinum Oxide as Active Sites in Hydrogen Evolution Reactions

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